Photochromic behaviour of poly[N,N-[(3-dimethylamino)propyl]methacrylamide] having spiroxazine pendant group

Sung-Hoon Kim; So-Yeon Park; Chang-Ju Shin

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Photochromic behaviour of poly[N,N-[(3-dimethylamino)propyl]methacrylamide] having spiroxazine pendant group

机译：具有螺恶嗪侧基的聚[N，N-[（3-二甲基氨基）丙基]甲基丙烯酰胺]的光致变色行为

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This work describes the synthesis and photochromic properties of poly[N,N-[(3-dimethylamino)propyl]methacrylamide] bearing spiroxa-zines.Spiroxazine group showed reversible isomerization in this polymer upon photoirradiation.Solution viscosity of the polymer was reduced during irradiation and returns to the initial value after removing the light in DMSO.The ionic conductivity in polymer solution gradually increased upon UV irradiation and subsequently decreased in the dark.

机译：这项工作描述了带有螺氧杂嗪的聚[N，N-[（3-二甲基氨基）丙基]甲基丙烯酰胺]的合成和光致变色性能。吡咯嗪基团在光辐照下显示可逆异构化，辐照过程中聚合物的溶液粘度降低在DMSO中除去光后，其返回初始值。聚合物溶液中的离子电导率在紫外线照射下逐渐增加，然后在黑暗中降低。

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《Dyes and Pigments》 |2007年第26期|共4页
作者
Sung-Hoon Kim; So-Yeon Park; Chang-Ju Shin;
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正文语种 eng
中图分类染料及中间体工业;
关键词
Spiroxazine polymer; Photochromism; Photoviscosity effect; First-order kinetics;

机译：吡咯嗪聚合物;光致变色;光粘度效应;一级动力学;

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1. Photochromic behaviour of poly[N,N-[(3-dimethylamino)propyl]methacrylamide] having spiroxazine pendant group [J] . Sung-Hoon Kim, So-Yeon Park, Chang-Ju Shin Dyes and Pigments . 2007,第26期

机译：具有螺恶嗪侧基的聚[N，N-[（3-二甲基氨基）丙基]甲基丙烯酰胺]的光致变色行为
2. Fabrication of thermoresponsive, core-crosslinked micelles based on poly[N-isopropyl acrylamide-co-3-(trimethoxysilyl)propylmethacrylate]-b-poly{N-[3-(dimethylamino)propyl]methacrylamide} for the codelivery of doxorubicin and nucleic acid [J] . Chang Cong, Dan Hong, Zhang Li-Ping, Journal of Applied Polymer Science . 2015,第15a16期

机译：基于聚[N-异丙基丙烯酰胺-甲基-3-（三甲氧基甲硅烷基）丙基甲基丙烯酸] -b-聚（N- [3-（二甲氨基）丙基]甲基丙烯酰胺}的热响应性核交联胶束的制备酸
3. Synthesis and characterization of poly{N-[3-(dimethylamino) propyl] methacrylamide-co-itaconic acid} hydrogels for drug delivery [J] . Mishra R.K., Ray A.R. Journal of Applied Polymer Science . 2011,第6期

机译：药物输送用聚{N- [3-（二甲基氨基）丙基]甲基丙烯酰胺-衣康酸}水凝胶的合成与表征
4. VINYL RADICAL POLYMERIZATION INITIATED WITH AMMONIUM PERSULFATE AND N-(3-DIMETHYLAMINO)PROPYL ACRYLAMIDE SYSTEMS [C] . Kun Si, Xin-Qiu Guo, Kun-Yuan Qiu Asia symposium on polymerization and fine polymers . 1995

机译：过硫酸铵和N-（3-二甲基亚氨基）丙基丙烯酰胺体系引发的乙烯基自由基聚合
5. Studies of the RAFT polymerization of acrylamide and N-[3-(dimethylamino)propyl] methacrylamide: Factors affecting kinetics, molecular weight control, and block copolymer formation. [D] . Thomas, David Bryan. 2003

机译：丙烯酰胺和N- [3-（二甲基氨基）丙基]甲基丙烯酰胺的RAFT聚合研究：影响动力学，分子量控制和嵌段共聚物形成的因素。
6. Poly(N-(2-Hydroxypropyl) Methacrylamide)-Valproic Acid Conjugates as Block Copolymer Nanocarriers [O] . Jawaher A. Alfurhood, Hao Sun, Christopher P. Kabb, -1

机译：聚（N-（2-羟丙基）甲基丙烯酰胺）-丙戊酸共轭作为嵌段共聚物纳米载体
7. The use of poly(N-[2-hydroxypropyl]-methacrylamide) hydrogel to repair a T10 spinal cord hemisection in rat: a behavioural, electrophysiological and anatomical examination [O] . Pertici, Vincent, Amendola, Julien, Laurin, Jérôme, 2013

机译：聚（N- [2-羟丙基]-甲基丙烯酰胺）水凝胶在大鼠中修复T10脊髓半切的用途：行为，电生理和解剖学检查
8. Skin Sensitization Study with a Mixture of 1,2-Ethanediamine, N-(-3-(trimethoxysilyl)-propyl)-,nN-((ethenylphenyl)methyl) derivs., Hydrochlorides and N-((3-Trimethoxysilyl)propyl)ethylene-diaminenin Methanol. [R] . 2015

机译：用1,2-乙二胺，N - （ - 3-（三甲氧基甲硅烷基） - 丙基） - ，nN - （（乙烯基苯基）甲基）衍生物，盐酸盐和N - （（3-三甲氧基甲硅烷基）丙基）的混合物进行皮肤致敏研究乙烯 - 二胺亚甲醇。

Photochromic behaviour of poly[N,N-[(3-dimethylamino)propyl]methacrylamide] having spiroxazine pendant group

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