首页> 外文期刊>Doklady. Physics >Fluid viscosity under confined conditions
【24h】

Fluid viscosity under confined conditions

机译:密闭条件下的流体粘度

获取原文
获取原文并翻译 | 示例
       

摘要

Closed equations of fluid transfer in confined conditions are constructed in this study using ab initio methods of nonequilibrium statistical mechanics. It is shown that the fluid viscosity is not determined by the fluid properties alone, but becomes a property of the "fluid-nanochannel walls" system as a whole. Relations for the tensor of stresses and the interphase force, which specifies the exchange by momentum of fluid molecules with the channel-wall molecules, are derived. It is shown that the coefficient of viscosity is now determined by the sum of three contributions. The first contribution coincides with the expression for the coefficient of the viscosity of fluid in the bulk being specified by the interaction of fluid molecules with each other. The second contribution has the same structure as the first one but is determined by the interaction of fluid molecules with the channel-wall molecules. Finally, the third contribution has no analog in the usual statistical mechanics of transport processes of a simple fluid. It is associated with the correlation of intermolecular forces of the fluid and the channel walls. Thus, it is established that the coefficient of viscosity of fluid in sufficiently small channels will substantially differ from its bulk value.
机译:在这项研究中,使用从头算的非平衡统计力学方法构造了封闭条件下的流体传输封闭方程。结果表明,流体粘度不是仅由流体性质决定,而是整体上成为“流体-纳米通道壁”系统的性质。推导了应力张量和相间力的关系,该关系指定了流体分子通过动量与通道壁分子的交换。结果表明,粘度系数现在由三个贡献之和确定。第一贡献与通过流体分子彼此的相互作用指定了本体中的流体的粘度系数的表达式相一致。第二部分与第一部分具有相同的结构,但取决于流体分子与通道壁分子的相互作用。最后,在简单的流体传输过程的通常统计力学中,第三项贡献没有类似之处。它与流体和通道壁的分子间力的相关性有关。因此,可以确定的是,足够小的通道中的流体的粘度系数将与其体积值显着不同。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号