Structure, photophysical properties and computational study of a highly luminescent mixed-metal platinum(ii)-silver(i) system. Potential building blocks for emissive supramolecular structures

摘要

A luminescent cyclometalated platinum(ii) complex has been shown to sandwich a silver ion, which demonstrates intense luminescence with appreciable photoluminescence quantum yield. Computational studies have been performed to provide insights into the nature of the photophysical properties.