Functionalized 1,2,3-triazoles as building blocks for photoluminescent POLOs (polymers of oligomers) of copper(I)

摘要

Two 3-D and one 2-D metal-organic frameworks [Cu8I8(L-1)(4)](n) (1), [Cu8I8(L-2)(4)](n) (2) and [Cu4I4(L-3)(2)](n) ( 3) were synthesized using three novel pyridine and pyrazole supported 1,2,3-triazoles, 1-(4-picolyl)-4-butyl-1H-1,2,3-triazole (L1), 1-(4-picolyl)-4-pentyl-1H-1,2,3-triazole( L2) and 1-(4-picolyl)-4-(3,5-dimethylpyrazolylmethyl)-1H-1,2,3-triazole (L3). In both complexes 1 and 2, there co-exist a 1-D Cu(I) oligomer and Cu-4 tetrahedron cluster in the 3-D polymeric structures. Complex 3 shows a 2-D (4, 4) net with the stair-step Cu4I4 as node and L3 as a building block. All three complexes exhibit photoluminescence.