Unexpected pincer-type coordination (kappa(3)-SBS) within a zerovalent platinum metallaboratrane complex

Owen GR; Gould PH; Hamilton A; Tsoureas N

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Unexpected pincer-type coordination (kappa(3)-SBS) within a zerovalent platinum metallaboratrane complex

机译：零价铂金属铂金络合物中发生意外的钳型配位（kappa（3）-SBS）

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摘要

The first structurally characterised zerovalent platinum complex to contain a tridentate pincer-type coordination mode (kappa(3)-SBS) is presented, raising further questions concerning the geometries and trans influence of Z-type ligands.

机译：提出了第一个结构特征为零价的铂配合物，其包含三齿钳型配位模式（kappa（3）-SBS），引发了有关Z型配体的几何形状和反式影响的进一步问题。

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《Dalton transactions: An international journal of inorganic chemistry 》 |2010年第1期| 共4页
作者
Owen GR; Gould PH; Hamilton A; Tsoureas N;
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正文语种 eng
中图分类化学 ;
关键词
POLYAZOLYL CHELATE CHEMISTRY; TRANSITION-METAL-COMPLEXES; DATIVE SIGMA-BOND; OXIDATIVE ADDITION; HYDRIDE MIGRATION; BORANE COMPLEXES; LEWIS BASICITY; BU-T; LIGAND; METHIMAZOLYL;

机译：聚唑基化学;过渡金属-络合物;天然西格马胶;氧化加成;氢化物迁移;硼烷络合物;路易斯碱;BU-T;配体;间苯二酚;

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1. Unexpected pincer-type coordination (kappa(3)-SBS) within a zerovalent platinum metallaboratrane complex [J] . Owen GR, Gould PH, Hamilton A, Dalton transactions: An international journal of inorganic chemistry . 2010 ,第1期

机译：零价铂金属铂金络合物中发生意外的钳型配位（kappa（3）-SBS）
2. Monodentate and Bridging Coordination of 3,3'-Annelated 2,2'-Bipyridines in Zerovalent Palladium- and Platinum-p-quinone Complexes [J] . Rene A. Klein, Peter Witte, Ruud van Belzen, European journal of inorganic chemistry . 1998 ,第3期

机译：零价钯-和铂-对苯醌络合物中3,3'-带环的2,2'-联吡啶的单齿和桥联配位
3. Successive formation of hydrido(germyl)platinum, germaplatinacycle, and germylene-bridged dinuclear platinum complexes from the reaction of a zerovalent platinum complex with alpha,omega-dihydrodigermanes [J] . Usui Y, Hosotani S, Ogawa A, Organometallics . 2005 ,第18期

机译：零价铂络合物与α，ω-二氢二聚二茂铁的反应，连续形成氢化（锗烷基）铂，germatplatinacycle和germ烯桥联的双核铂络合物
4. The Reaction of a Zerovalent Platinum Complex with 1,2-Dihydrodisilane [C] . Aki Noda, Makiko Takahashi, Mayumi Yoshida Symposium on Organometallic Chemistry . 2007

机译：Zeropalent铂络合物与1,2-二氢硅烷的反应
5. Synthesis and characterization of a series of novel platinum coordination complexes of the type cis-[platinum(ammonia)(2)(N-Het)chlorine]nitrate with methyl-substituted thiazoles and benzothiazoles. [D] . Hernandez Castillo, Ramon Luis. 2004

机译：合成和表征了一系列新型的顺式[[氨（氨）（2）（N-Het）氯]硝酸盐]硝酸盐与甲基取代的噻唑和苯并噻唑的铂配位配合物。
6. Retinoic Acid-Platinum (II) Complex RT-Pt(II) Protects Against Rheumatoid Arthritis in Mice via MEK/Nuclear Factor kappa B (NF-κB) Pathway Downregulation [O] . Ziqiang Cui, Yaping Lin, Yuhong Liu, 2020

机译：视黄酸 - 铂（II）复合物RT-Pt（II）通过MEK /核因子Kappa B（NF-κB）途径下调来保护针对小鼠的类风湿性关节炎
7. Unexpected Photoisomerization of a Pincer-type Amido Ligand Leads to Facial Coordination at Pt(IV) [O] . Harkins Seth B., Peters Jonas C. 2006

机译：钳型酰胺配体的意外光致异构化导致Pt（IV）的面部协调。
8. Metallaborane Chemistry. Part 9. Oxidative-insertion Reactions of Zerovalent Nickel and Platinum Complexes with 1,7-Dicarbacloso-octaborane, 4,5-Dicarba-closo-nonaborane, 1,6-Dicarba-closo-decaborane, and their C-Methyl Derivative [R] . Green, M., Spencer, J. L., Stone, F. G. A. 1978

机译：金属硼烷化学。第9部分。零价镍和铂配合物与1,7-二十二碳四烯，4,5-二十碳 - 叔丁基，1,6-二十碳 - 十碳硼烷及其C-甲基衍生物的氧化 - 插入反应

Unexpected pincer-type coordination (kappa(3)-SBS) within a zerovalent platinum metallaboratrane complex

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