Acetate-controlled demetalation in multiiron polyoxometalates: A triiron cluster trapped between β- and γ-Keggin isomers

Bogdan Botar; Arkady Ellern; Paul K_gerler

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Acetate-controlled demetalation in multiiron polyoxometalates: A triiron cluster trapped between β- and γ-Keggin isomers

机译：多铁多金属氧酸盐中乙酸盐控制的脱金属：困在β-和γ-Keggin异构体之间的三铁簇

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摘要

Acetate-induced demetalation of a {γ-SiW_(10)Fe~2}-based dimer affords an acetato/hydroxo-bridged triiron cluster stabilized by two isomerically distinct Keggin units.

机译：醋酸盐诱导的基于{γ-SiW_（10）Fe〜2}的二聚体的脱金属作用提供了由两个异构的不同Keggin单元稳定的乙酰/羟基桥接的三铁簇。

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来源
《Dalton transactions: An international journal of inorganic chemistry 》 |2009年第29期| 共3页
作者
Bogdan Botar; Arkady Ellern; Paul K_gerler;
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正文语种 eng
中图分类 540C0007-A;
关键词
Acetate-controlled demetalation; multiiron polyoxometalates; isomers;

机译：醋酸盐控制的脱金属;多铁多金属氧酸盐;异构体;

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1. Acetate-controlled demetalation in multiiron polyoxometalates: A triiron cluster trapped between β- and γ-Keggin isomers [J] . Bogdan Botar, Arkady Ellern, Paul K_gerler Dalton transactions: An international journal of inorganic chemistry . 2009 ,第29期

机译：多铁多金属氧酸盐中乙酸盐控制的脱金属：困在β-和γ-Keggin异构体之间的三铁簇
2. Trapping the delta Isomer of the Polyoxometalate-Based Keggin Cluster with a Tripodal Ligand [J] . Sartzi Harikleia, Miras Haralampos N., Vila-Nadal Laia, Angewandte Chemie . 2015 ,第51期

机译：用三脚架配体捕获基于多金属氧酸盐的Keggin簇的δ异构体
3. Acetate-driven polyoxometalate demetalation: An open-shell diiron polytungstate comprising two rotational Keggin isomers [J] . Botar B, Kogerler P Dalton transactions: An international journal of inorganic chemistry . 2008 ,第24期

机译：乙酸盐驱动的多金属氧酸盐脱金属：包含两个旋转的Keggin异构体的开壳二铁多钨酸盐
4. ELECTROPOLYMERISED ARCHITECTURE ENTRAPING A TRILACUNARY KEGGIN-TYPE POLYOXOMETALATE FOR ASSEMBLING A GLUCOSE BIOSENSOR [C] . Graziella Liana TURDEAN, Antonella CURULLI, Ionel Catalin POPESCU, International Symposium on Chemical and Biological Sensors and Analytical Methods II, 2001 . 2001

机译：封装了糖基化生物传感器的三聚氰胺甲酸酯型电聚合结构
5. Fabrication of Keggin type polyoxometalate ultrathin films and highly porous titanium dioxide films using layer-by-layer self assembly technique. [D] . Shaik, Shafi. 2006

机译：使用逐层自组装技术制备Keggin型多金属氧酸盐超薄膜和高孔隙度二氧化钛薄膜。
6. Transformation of Tri-Titanium(IV)-Substituted α-Keggin Polyoxometalate (POM) into Tetra-Titanium(IV)-Substituted POMs : Reaction Products of Titanium(IV) Sulfate with the Dimeric Keggin POM Precursor under Acidic Conditions [O] . Yuki Mouri, Yoshitaka Sakai, Yoshitaka Kobayashi, 2010

机译：三钛（IV）取代的α-Keggin多金属氧酸盐（POM）转变为四钛（IV）取代的POM：酸性条件下硫酸钛（IV）与二聚Keggin POM前体的反应产物
7. Trapping the δ isomer of the polyoxometalate-based Keggin cluster with a tripodal ligand [O] . Sartzi, Harikleia, Miras, Haralampos N., Vila-Nadal, Laia, 2015

机译：用三足配体捕获基于多金属氧酸盐的Keggin簇的δ异构体
8. Models for Heteropoly Blues. Degrees of Valence Trapping in Vanadium(IV)- and Molybdenum(V)-Substituted Keggin Anions. [R] . Altenau, J. J., Pope, M. T., Prados, R. A., 1974

机译：Heteropoly Blues的模型。钒（IV） - 和钼（V） - 取代的Keggin阴离子中的价态捕获程度。

Acetate-controlled demetalation in multiiron polyoxometalates: A triiron cluster trapped between β- and γ-Keggin isomers

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