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1,2,3,4-tetrahydroquinolines as substrates for Mannich compounds [German]

机译:1,2,3,4-四氢喹啉作为曼尼希化合物的底物[德语]

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摘要

The product of the reaction of 1,2,3,4-tetrahydroquinoline (1) with 2-naphthoi (2) and formaldehyde reported as the N-substituted tetrahydroquinoline 3 shows really the structure of the phenylogous bis-substituted tetrahydroquinoline 4. The function of 1, 6-methyl-1,2,3,4-tetrahydroquinoline (9) and 1-methyl-1,2,3, 1-tetrahydroquinoline (17) as amines or C-nucleophilic compounds in Mannich condensations were examined. [References: 3]
机译:1,2,3,4-四氢喹啉(1)与2-萘酚(2)和甲醛的反应产物,据报道是N-取代的四氢喹啉3,实际上显示了苯二双取代的四氢喹啉4的结构。功能检查了曼尼希缩合反应中作为胺或C-亲核化合物的1,6-甲基-1,2,3,4-四氢喹啉(9)和1-甲基-1,2,3,1-四氢喹啉(17)。 [参考:3]

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