Study of multiwalled graphite nanotubes and filaments formation from carbonized products of polyvinyl alcohol via catalytic graphitization at 600-800 degrees C in nitrogen atmosphere

摘要

The catalytic graphitization of amorphous carbon matrix was carried out at the temperature range of 600-800 degrees C in nitrogen atmosphere. Amorphous carbon matrix with uniformly distributed Fe particles was obtained via catalytic carbonization of polyvinyl alcohol (PVA) at temperatures up to 600 degrees C in nitrogen atmosphere. Using transmission electron microscopy (TEM), selected area diffraction (SAD), scanning electron microscopy (SEM), and X-ray diffractometry (XRD), graphite structures of three types were found in products of catalytic graphitization of amorphous carbon matrix: multiwalled graphite shells wrapping the catalyst particles, cockle-shelled graphite filaments (CSF), and multiwalled graphite nanotubes (MWNT). We suppose that the formation of CSF proceeds through the dissolution of amorphous carbon in the metal, transformation of the catalyst particles into a liquid state, and transfer of dissolved carbon via intermediates to growing filaments. Graphite nanotubes nucleate at the matrix surface and then grow in the porous space of the matrix. (C) 2000 Elsevier Science Ltd. All rights reserved. [References: 22]