The #alpha#-Effect Of Oximate Ions And Solvent Effect In The Transfer Of The Toluenesulfonyl Group In Aqueous Dimenthylsulfoxide

Yu.S.Simanenko; T.M.Zubareva; I.P.Suprun; T.M.Prokopeva; A.F.Popov; E.A.Karpichev

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The #alpha#-Effect Of Oximate Ions And Solvent Effect In The Transfer Of The Toluenesulfonyl Group In Aqueous Dimenthylsulfoxide

机译：二甲氧基亚砜中甲苯磺酸根基转移的氧代离子的α-效应和溶剂效应

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The kinetic behavior of oximate ions was studied in the transfer of the toluenesulfonyl group in aqueous dimethylsulfoxide (0-95 vol.% DMSO). The solvation effects of the solvent are a factor controlling the nucleophilicity and magnitude of the #alpha#-effect of the oximate ions.

机译：在甲苯磺酰基在二甲基亚砜水溶液（0-95体积％DMSO）中的转移中研究了肟酸根离子的动力学行为。溶剂的溶剂化作用是控制肟酸离子的＃alpha＃效应的亲核性和大小的因素。

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《Theoretical and Experimental Chemistry》 |2000年第1期|共6页
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Yu.S.Simanenko; T.M.Zubareva; I.P.Suprun; T.M.Prokopeva; A.F.Popov; E.A.Karpichev;
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1. The #alpha#-Effect Of Oximate Ions And Solvent Effect In The Transfer Of The Toluenesulfonyl Group In Aqueous Dimenthylsulfoxide [J] . Yu.S.Simanenko, T.M.Zubareva, I.P.Suprun, Theoretical and Experimental Chemistry . 2000,第1期

机译：二甲氧基亚砜中甲苯磺酸根基转移的氧代离子的α-效应和溶剂效应
2. THE EFFECT OF SOLVENT ON THE ALPHA-EFFECT - ABNORMAL NUCLEOPHILIC REACTIVITY OF SUBSTITUTED ACETOPHENONE OXIMATE ANIONS IN AQUEOUS DMSO [J] . Um IH., Kwon DS., Oh SJ. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1995,第38期

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7. Study of electrolytic solution process using the scaled particle theory. 4. Standard free energy of transfer from aqueous to mixed aqueous binary solvent systems [O] . Utpal Sen 1984

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The #alpha#-Effect Of Oximate Ions And Solvent Effect In The Transfer Of The Toluenesulfonyl Group In Aqueous Dimenthylsulfoxide

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