Miscibility study in stable and metastable orientational disordered phases in a two-component system (CH_3)CCl_3 + CCl_4

摘要

The orientationally disordered stable and metastable mixed crystals of the two-component system methylchloroform ((CH_3)CCl_3) + carbon tetrachloride (CCl_4) have been characterised from a crystallographic and thermodynamic point of view. The monotropic behaviour of the metastable phase in the pure components is maintained for the whole range of composition. The lattice symmetry of the stable orientationally disordered phase of methylchloroform has been found to be isostructural with that of the carbon tetrachloride compound. Continuous series of both stable and metastable mixed crystals give rise to a double isomorphism relationship, one for the stable state and another for the metastable stable of the pure components.