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Nucleation at high pressure. II. Wave tube data and analysis

机译:在高压下成核。二。波管数据和分析

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Nucleation rate data, obtained from expansion wave tube experiments, are reported for several vapor-gas mixtures at high pressure. Results are given for water-vapor in the presence of helium and nitrogen gas, and for n-nonane in helium and methane. For all these mixtures, carrier gas pressures of 10, 25, and 40 bar have been applied, with temperatures ranging from 230 to 250 K. An extended form of the nucleation theorem (in terms of the derivative of the nucleation rate with respect to carrier gas pressure) is derived, which appears to be very helpful in the interpretation of high pressure data. It can be used to obtain the carrier gas content of the critical nucleus directly from the pressure dependence dependence of experimental nucleation rates. Combining this method with the theoretical considerations of part I of this paper [J. Chem. Phys. 111, 8524 (1999), preceding paper]: the nucleation behavior of water at high pressures of both helium and nitrogen can quantitatively be understood. For n-nonane in helium our "pressure perturbation approach" is also valid. For n-nonane in methane, however, this approach fails because of the high methane solubility in the liquid phase.
机译:从膨胀波管实验获得的成核率数据已报告为几种高压蒸气混合物的结果。给出了存在氦气和氮气的水蒸气,以及存在于氦气和甲烷中的正壬烷的结果。对于所有这些混合物,已施加10、25和40 bar的载气压力,温度范围为230至250K。成核定理的扩展形式(根据成核速率相对于载体的导数表示)气体压力),这对解释高压数据非常有帮助。它可以直接从实验成核速率的压力依赖性中获得临界核的载气含量。将该方法与本文第一部分的理论考虑相结合[J.化学物理111,8524(1999),先前的论文]:可以定量地理解水在氦和氮的高压下的成核行为。对于氦气中的正壬烷,我们的“压力扰动法”也是有效的。但是,对于甲烷中的正壬烷,由于甲烷在液相中的溶解度高,因此该方法失败。

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