SPECTROSCOPY OF THE FLUOROMETHYLENE RADICALS HCF AND DCF BY 2+1 RESONANCE ENHANCED MULTIPHOTON IONIZATION SPECTROSCOPY AND BY AB INITIO CALCULATION

Irikura KK.; Johnson RD.; Hudgens JW.

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SPECTROSCOPY OF THE FLUOROMETHYLENE RADICALS HCF AND DCF BY 2+1 RESONANCE ENHANCED MULTIPHOTON IONIZATION SPECTROSCOPY AND BY AB INITIO CALCULATION

机译：2 + 1共振多光子电离光谱和从头算计算的氟自由基HCF和DCF的光谱

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Spectra of fluoromethylene radicals, HCF and DCF, have been observed between 304 and 325 nm using mass-resolved, resonance enhanced multiphoton ionization (REMPI). Singlet HCF is generated by sequential reactions of atomic fluorine in either methane or methyl fluoride. The spectra arise from two-photon resonances between the ground state X (

机译：使用质量分辨的，共振增强的多光子电离（REMPI），已在304至325 nm之间观察到了氟亚甲基自由基HCF和DCF的光谱。单峰HCF是通过原子氟在甲烷或甲基氟中的顺序反应生成的。光谱是由基态X（

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《The Journal of Chemical Physics》 |1995年第4期|共6页
作者
Irikura KK.; Johnson RD.; Hudgens JW.;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
Laser-induced fluorescence; Singlet-triplet separations; Excitation spectroscopy; Vibrational frequencies; Halocarbenes chf; States; Luminescence; Assignments; Energetics; Geometries;

机译：激光诱导的荧光;三重峰-三重分离;激发光谱;振动频率;卤代卡宾chf;状态;发光;赋值;能量学;几何;

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1. SPECTROSCOPY OF THE FLUOROMETHYLENE RADICALS HCF AND DCF BY 2+1 RESONANCE ENHANCED MULTIPHOTON IONIZATION SPECTROSCOPY AND BY AB INITIO CALCULATION [J] . Irikura KK., Johnson RD., Hudgens JW. The Journal of Chemical Physics . 1995,第4期

机译：2 + 1共振多光子电离光谱和从头算计算的氟自由基HCF和DCF的光谱
2. A STUDY ON THE STRUCTURE AND VIBRATIONS OF DIPHENYLAMINE BY RESONANCE-ENHANCED MULTIPHOTON IONIZATION SPECTROSCOPY AND AB INITIO CALCULATIONS [J] . Boogaarts MGH., Meijer G., Vonhelden G. The Journal of Chemical Physics . 1996,第19期

机译：共振增强多光子电离光谱和从头算的研究二苯胺的结构和振动
3. Ab initio calculation of (2+1) resonance enhanced multiphoton ionization spectra and lifetimes of the (D,3)(2)Sigma(-) states of OH and OD [J] . van der Loo MPJ, Groenenboom GC The Journal of Chemical Physics . 2005,第7期

机译：从头算的（2 + 1）共振增强多光子电离光谱和OH和OD（D，3）（2）Sigma（-）状态的寿命
4. New ways to optically detect CH2 and HCF radicals using resonance-enhanced multiphoton ionization spectroscopy [C] . Jeffrey W. Hudgens, National Institute of Standards, Technology, Conference on laser techniques for state-selected and state-to-state chemistry . 1993

机译：使用共振增强多光子电离光谱法光学检测CH2和HCF自由基的新方法
5. Molecular spectroscopy and dynamics of reactive chemical intermediates studied using laser induced fluorescence (LIF), single vibronic level (SVL) emission and resonance enhanced multiphoton ionization (REMPI) spectrometry [D] . Muzangwa, Lloyd G. 2013

机译：使用激光诱导荧光（LIF），单电子能级（SVL）发射和共振增强多光子电离（REMPI）光谱研究的反应性化学中间体的分子光谱和动力学
6. Vibronic structure of photosynthetic pigments probed by polarized two-dimensional electronic spectroscopy and ab initio calculations [O] . Yin Song, Alexander Schubert, Elizabeth Maret, 2019

机译：偏振二维电子光谱探测光合色素的振动结构和从头算
7. A study on the structure and vibrations of diphenylamine by resonance-enhanced multiphoton ionization spectroscopy and ab initio calculations [O] . Boogaarts, M.G.H., Helden, G.J. von, Meijer, G.J.M. 1996

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8. In situ Radical Detection under Very Low Pressure Photolysis Conditions Using Resonance-Enhanced Multiphoton Ionization. Kinetics of CF3 Radicals Produced from IR Multiphoton Dissociation of Hexafluoroacetone [R] . Robertson, R. M., Golden, D. M., Rossi, M. J. 1988

机译：基于共振增强多光子电离的极低压光解条件下原位自由基检测。六氟丙酮红外多光子解离产生CF3自由基的动力学

SPECTROSCOPY OF THE FLUOROMETHYLENE RADICALS HCF AND DCF BY 2+1 RESONANCE ENHANCED MULTIPHOTON IONIZATION SPECTROSCOPY AND BY AB INITIO CALCULATION

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