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Wetting, spreading, and adsorption on randomly rough surfaces

机译:在随机粗糙的表面上润湿,扩散和吸附

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摘要

The wetting properties of solid substrates with customary (i.e., macroscopic) random roughness are considered as a function of the microscopic contact angle of the wetting liquid and its partial pressure in the surrounding gas phase. Analytic expressions are derived which allow for any given lateral correlation function and height distribution of the roughness to calculate the wetting phase diagram, the adsorption isotherms, and to locate the percolation transition in the adsorbed liquid film. Most features turn out to depend only on a few key parameters of the roughness, which can be clearly identified. It is shown that a first-order transition in the adsorbed film thickness, which we term "Wenzel prewetting", occurs generically on typical roughness topographies, but is absent on purely Gaussian roughness. It is thereby shown that even subtle deviations from Gaussian roughness characteristics may be essential for correctly predicting even qualitative aspects of wetting.
机译:具有常规(即宏观)随机粗糙度的固体基质的润湿性能被认为是润湿液的微观接触角及其在周围气相中的分压的函数。导出解析表达式,该表达式允许任何给定的横向相关函数和粗糙度的高度分布,以计算润湿相图,吸附等温线,并确定被吸附液膜中的渗透转变。事实证明,大多数特征仅取决于粗糙度的几个关键参数,这些参数可以清楚地识别出来。结果表明,吸附膜厚度的一阶跃迁(通常称为“ Wenzel预湿润”)通常发生在典型的粗糙度形貌上,而在纯高斯粗糙度中则不存在。由此表明,即使是高斯粗糙度特征的细微偏差对于正确预测润湿的定性方面也可能至关重要。

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