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Solid State Ionics

机译:固态离子

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摘要

Solid state ionics (the transport of ions in solids) is not only a major focus of the High Temperature Materials (HTM) Division but also plays a role in most other ECS Divisions. For instance, the flux of oxygen ions through ceramic Ion Transport Membranes (ITMs) and Solid Oxide Fuel Cells (SOFCs) under open circuit conditions is governed by the Wagner equation: where J_(o2) is the O2 flux, P_(o2) is the O_2 partial pressure, R and F are the gas and Faraday's constants, T is temperature, L the thickness of the membrane or film, and sigma_e and sigma_v are the conductivities of electrons and oxygen vacancies, respectively.
机译:固态离子(固体中离子的运输)不仅是高温材料(HTM)部门的主要重点,而且在大多数其他ECS部门中也发挥着作用。例如,在开路条件下,通过陶瓷离子传输膜(ITM)和固体氧化物燃料电池(SOFC)的氧离子通量受Wagner方程控制:其中J_(o2)是O2通量,P_(o2)是O_2分压,R和F是气体和法拉第常数,T是温度,L是膜或膜的厚度,sigma_e和sigma_v分别是电子和氧空位的电导率。

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