首页> 外文期刊>The Analyst: The Analytical Journal of the Royal Society of Chemistry: A Monthly International Publication Dealing with All Branches of Analytical Chemistry >An experimental study on the influence of trace impurities on ionization of atmospheric noble gas dielectric barrier discharges
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An experimental study on the influence of trace impurities on ionization of atmospheric noble gas dielectric barrier discharges

机译:微量杂质对大气惰性气体介电势垒放电电离影响的实验研究

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摘要

While the influence of trace impurities in noble gas discharges is well established in theoretical work, experimental approaches are difficult. Particularly the effects of trace concentrations of N-2 on He discharges are complicated to investigate due to the fact that for He 5.0 the purity of He is only 99.999%. This corresponds to a residual concentration of 10 ppm, thereof 3 ppm of N-2, in He. Matters are made difficult by the fact that He DBD plasmajets are normally operated under an ambient atmosphere, which has a high abundance of N-2. This work tackles these problems from two sides. The first approach is to operate a DBD plasmajet under a quasi-controlled He atmosphere, therefore diminishing the effect of atmospheric N-2 and making a defined contamination with N-2 possible. The second approach is using Ar as the operating gas and introducing propane (C3H8) as a suitable substitute impurity like N-2 in He. As will be shown both discharges in either He or Ar, with their respective impurity show the same qualitative behaviour.
机译:尽管在理论工作中已充分确立了稀有气体排放中微量杂质的影响,但实验方法却很困难。特别是痕量的N-2对He放电的影响很难研究,因为对于He 5.0,He的纯度仅为99.999%。这对应于He中的残留浓度为10 ppm,其中N-2为3 ppm。 He DBD等离子喷嘴通常在具有高N-2含量的周围环境下运行,这使事情变得困难。这项工作从两个方面解决了这些问题。第一种方法是在准受控的He气氛下操作DBD等离子射流,因此减少了N-2大气的影响,并可能导致N-2的明确污染。第二种方法是使用Ar作为工作气体,并在He中引入丙烷(C3H8)作为合适的替代杂质,例如N-2。如将显示的那样,在He或Ar中的两种放电,以及它们各自的杂质都显示出相同的定性行为。

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