CONTRASTING REACTIVITY IN LEWIS ACID-PROMOTED REACTIONS OF THIO- AND SILYL-ALLENES WITH 1,4-BENZOQUINONES

Engler TA.; Reddy JP.; Iyengar R.; Agrios K.

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CONTRASTING REACTIVITY IN LEWIS ACID-PROMOTED REACTIONS OF THIO- AND SILYL-ALLENES WITH 1,4-BENZOQUINONES

机译：路易斯酸与1,4-苯甲醌对硫代和甲硅烷基的酸反应中的对比反应性

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In Ti(IV)-promoted reactions with 2-methoxy-1,4-benzoquinones 3, thioallenes I give 2+2 and/or 3+2 products via attack on a C=C moiety of the quinone, whereas silylallene 2 gives products derived from attack on a carbonyl group of the quinone. [References: 24]

机译：在Ti（IV）促进的与2-甲氧基-1,4-苯醌3的反应中，硫代丙二烯I通过攻击醌的C = C部分产生2 + 2和/或3 + 2产物，而甲硅烷基丙二烯2产生产物由攻击醌的羰基衍生而来。 [参考：24]

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |1996年第3期|共4页
作者
Engler TA.; Reddy JP.; Iyengar R.; Agrios K.;
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正文语种 eng
中图分类有机化学;
关键词
(trimethylsilyl)cyclopentene annulation; Stereochemical course; Allylation; Quinones; Alcohols; Scope;

机译：（三甲基甲硅烷基）环戊烯环化;立体化学过程;烯丙基化;喹诺酮;醇;范围;

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1. CONTRASTING REACTIVITY IN LEWIS ACID-PROMOTED REACTIONS OF THIO- AND SILYL-ALLENES WITH 1,4-BENZOQUINONES [J] . Engler TA., Reddy JP., Iyengar R., Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1996,第3期

机译：路易斯酸与1,4-苯甲醌对硫代和甲硅烷基的酸反应中的对比反应性
2. SWITCHABLE REGIOSELECTIVITY IN LEWIS ACID-PROMOTED REACTIONS OF 1,4-BENZOQUINONE MONOIMIDES WITH STYRENYL SYSTEMS - SELECTIVE SYNTHESES OF EITHER 2-ARYL-2,3-DIHYDROBENZOFURANS OR 2-ARYL-2,3-DIHYDROINDOLES [J] . Engler TA., Lynch KO., Chai WY. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1995,第39期

机译：1,4-苯并甲醌单酰亚胺与苯乙烯基体系的路易斯酸促进反应中的可切换区域选择性-2-ARYL-2,3-二氢苯并呋喃或2-ARYL-2,3-二氢吲哚的选择性合成
3. Lewis Acid-Promoted Reactions of Styrenyl Systems with Benzoquinone Bisimines: New Regioselective Syntheses of Substituted 2-Aryl-2,3-dihydroindoles and 2-Arylindoles [J] . Thomas A. Engler, Steven P. Meduna, Kenneth O. LaTessa, The Journal of Organic Chemistry . 1996,第24期

机译：刘易斯酸促进的苯乙烯基系统与苯醌双嘧啶的反应：取代的2-芳基-2,3-二氢吲哚和2-Arylindoles的新的区域选择性合成。
4. Alternating Copolymerizations of 9,10-Anthraquinone diketene or 1,4-Naphthoquinone diketene with 1,4-Benzoquinone or 1,4-Benzoquinone diimine: A Novel Preparative Route for Polyarylate and Polyaramide [C] . Shouji Iwatsuki, Takahito Itoh, Masahiko Kozaki Asia symposium on polymerization and fine polymers . 1995

机译：9,10-蒽醌二酮或1,4-萘醌二酮与1,4-苯醌或1,4-苯醌二亚胺的交替共聚：聚芳酯和聚芳酰胺的新型制备方法
5. I. Synthesis of new thio- and selenoglycosides towards glycomimetics and enzyme inhibition. II. Preparations and reactions of thio- and selenocarboxylates. III. Synthesis of mycothiol analogues. [D] . Darout, Etzer. 2005

机译：I.针对糖模拟物和酶抑制的新的硫代和硒代糖苷的合成。二。硫代和硒代羧酸盐的制备和反应。三，麦硫酚类似物的合成。
6. Lewis Acid-Promoted Friedel-Crafts Alkylation Reactions with α-Ketophosphate Electrophiles [O] . Austin G. Smith, Jeffrey S. Johnson -1

机译：路易斯酸促进的傅克烷基化反应与α-Ketophosphate亲电
7. The unique regioselectivity in the formation of disubstituted-1,4-benzoquinones generated from the reaction of 4-hydroxycoumarins with 1,4-benzoquinone [O] . Zhang SL, Huang ZS, Shen YD, 2006

机译：4-羟基香豆素与1,4-苯醌反应生成的二取代-1,4-苯醌形成中的独特区域选择性

CONTRASTING REACTIVITY IN LEWIS ACID-PROMOTED REACTIONS OF THIO- AND SILYL-ALLENES WITH 1,4-BENZOQUINONES

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