TOTAL SYNTHESES OF HYMENIALDISINE AND DEBROMOHYMENIALDISINE - STEREOSPECIFIC CONSTRUCTION OF THE 2-AMINO-4-OXO-2-IMIDAZOLIN-5(Z)-DISUBSTITUTED YLIDENE RING SYSTEM

Annoura H.; Tatsuoka T.

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TOTAL SYNTHESES OF HYMENIALDISINE AND DEBROMOHYMENIALDISINE - STEREOSPECIFIC CONSTRUCTION OF THE 2-AMINO-4-OXO-2-IMIDAZOLIN-5(Z)-DISUBSTITUTED YLIDENE RING SYSTEM

机译：羟乙二胺和去溴乙二胺的总合成-2-氨基-4-氧代-2-咪唑啉-5（Z）-二亚乙基环体系的立体比构型

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The first total synthesis of hymenialdisine (1a) and debromolymenialdisine (Ib) was achieved via a novel stereospecific construction of the 2-amino-4-oxo-2-imidazoline-5(Z)-disubstituted ylidene ring system. [References: 27]

机译：通过2-氨基-4-氧代-2-咪唑啉-5（Z）-二取代的亚芳基环系统的新型立体定向结构，实现了膜虫碱（1a）和膜溴虫碱（Ib）的首次全合成。 [参考：27]

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |1995年第3期|共4页
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Annoura H.; Tatsuoka T.;
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正文语种 eng
中图分类有机化学;
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Aplysinopsin-type alkaloids; Marine natural-products; Family dendrophylliidae; Bromo-compound; Sponge; Metabolites; 6; 7-dihydropyrrolo)2; 3-cgt; azepine-4; 8(1h; 5h)-dione; (z)-2-amino-4-arylmethylene-2-imidazolin-5-ones; Photoisomerization; Invertebrates;

机译：芹菜素型生物碱;海洋天然产物;树突科;溴化合物;海绵;代谢产物;6;7-二氢吡咯并）2;3-c氮杂-4;8（1h;5h）-二酮;（z）- 2-氨基-4-芳基亚甲基-2-咪唑啉-5-酮;光异构化;无脊椎动物;

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1. TOTAL SYNTHESES OF HYMENIALDISINE AND DEBROMOHYMENIALDISINE - STEREOSPECIFIC CONSTRUCTION OF THE 2-AMINO-4-OXO-2-IMIDAZOLIN-5(Z)-DISUBSTITUTED YLIDENE RING SYSTEM [J] . Annoura H., Tatsuoka T. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1995,第3期

机译：羟乙二胺和去溴乙二胺的总合成-2-氨基-4-氧代-2-咪唑啉-5（Z）-二亚乙基环体系的立体比构型
2. A New Glycociamidine Ring Precursor:Syntheses of (Z)-Hymenialdisine,(Z)-2-Debromohymenialdisine,and (+-)-endo-2-Debromohymenialdisine [J] . Gianluca Papeo, Helena Posteri, Daniela Borghi, Organic letters . 2005,第25期

机译：一种新的甘氨酰胺m环前体：（Z）-羟乙二胺，（Z）-2-脱溴羟乙二胺和（+-）-内-2--2-溴羟乙二胺的合成
3. Efficient and selective formation of macrocyclic disubstituted Z alkenes by ring-closing metathesis (RCM) reactions catalyzed by Mo- or W-based monoaryloxide pyrrolide (MAP) complexes: Applications to total syntheses of epilachnene, yuzu lactone, ambrettolide, epothilone C, and nakadomarin A [J] . Wang C., Yu M., Kyle A.F., Chemistry: A European journal . 2013,第8期

机译：通过基于Mo或W的单芳氧基吡咯化物（MAP）配合物催化的闭环复分解（RCM）反应有效且选择性地形成大环二取代Z烯烃一种
4. TOTAL ALGEBRAIC SYSTEM IDENTIFICATION FOR HOMOGENEOUS CATALYZED SYNTHESES OF FINE CHEMICALS (ALKENES TO ALDEHYDES) [C] . EFFENDI WIDJAJA, CHUANZHAO LI, MARC GARLAND International Conference on Scientific amp; Engineering Computation IC-SEC 2002 Dec 3-5, 2002 Singapore . 2002

机译：精细化工（烯烃到醛）的均相催化合成的总代数系统识别
5. Part I. The enantiospecific total synthesis of tryprostatin A and B as well as their enantiomers and mismatched pairs. Part II. The enantiospecific, stereospecific total synthesis of the ring-A oxygenated sarpagine indole alkaloids (+)-majvinine, (+)-10-methoxyaffinisine and (+)-N(a)-methylsarpagine as well as the first total synthesis of the Alstonia bisindole alkaloid macralstonidine [D] . Zhao, Shuo 2007

机译：第一部分。Tryprostatin A和B及其对映异构体和错配对的对映体特异性合成。第二部分对映体，立体有择的环A氧化的沙鲁帕辛吲哚生物碱（+）-majvinine，（+）-10-甲氧基affinisine和（+）-N（a）-甲基sarpagine的全合成以及Alstonia bisindole的第一个全合成生物碱Macralstonidine
6. Efficient and Selective Formation of Macrocyclic Disubstituted Z Alkenes by Ring-Closing Metathesis (RCM) Reactions Catalyzed by Mo- or W-Based Monoaryloxide Pyrrolide (MAP) Complexes. Applications to Total Syntheses of Epilachnene Yuzu Lactone Ambrettolide Epothilone C and Nakadomarin A [O] . Chenbo Wang, Miao Yu, Andrew F. Kyle, -1

机译：通过大环二取代烯烃Ž的高效和选择性形成闭环由钼或钨为基础的monoaryloxide吡咯（map）配合物催化复分解反应（RCm）反应。应用Epilachnene的全合成柚子内酯黄葵内酯埃博霉素C和那卡多莫林一
7. Efficient and selective formation of macrocyclic disubstituted Z alkenes by ring-closing metathesis (RCM) reactions catalyzed by Mo- or W-based monoaryloxide pyrrolide (MAP) complexes: applications to total syntheses of epilachnene, yuzu lactone, ambrettolide, epothilone C, and nakadomarin A. [O] . Wang, C, Yu, M, Kyle, AF, 2013

机译：Mo基或W基单芳氧基吡咯化物（MAP）配合物催化的闭环复分解（RCM）反应有效且选择性地形成大环二取代Z烯烃一个。

TOTAL SYNTHESES OF HYMENIALDISINE AND DEBROMOHYMENIALDISINE - STEREOSPECIFIC CONSTRUCTION OF THE 2-AMINO-4-OXO-2-IMIDAZOLIN-5(Z)-DISUBSTITUTED YLIDENE RING SYSTEM

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