Synthetic applications of the cyclic iminocarbonate rearrangement: enantioselective syntheses of chloramphenicol and 4-epi-cytoxazone

Park Jung Nam; Ko Soo Y.; Koh Hun Y.

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Synthetic applications of the cyclic iminocarbonate rearrangement: enantioselective syntheses of chloramphenicol and 4-epi-cytoxazone

机译：环状亚氨基碳酸酯重排的合成应用：氯霉素和4-表-胞x酮的对映选择性合成

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Chloramphenicol and 4-epi-cytoxazone have been enantioselectively synthesized using the asymmetric dihydroxylation and the cyclic iminocarbonate rearrangement as key steps.

机译：使用不对称二羟基化和环状亚氨基碳酸酯重排作为关键步骤，对映体选择性合成了氯霉素和4-表-胞x酮。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry 》 |2000年第29期| 共4页
作者
Park Jung Nam; Ko Soo Y.; Koh Hun Y.;
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正文语种 eng
中图分类有机化学 ;
关键词
enantioselective synthesis; cyclic iminocarbonate rearrangement; regioselection; chloramphenicol; 4-epi-cytoxazone;

机译：对映选择性合成;环状亚氨基碳酸酯重排;区域选择;氯霉素;4-表;

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1. Synthetic applications of the cyclic iminocarbonate rearrangement: enantioselective syntheses of chloramphenicol and 4-epi-cytoxazone [J] . Park Jung Nam, Ko Soo Y., Koh Hun Y. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2000 ,第29期

机译：环状亚氨基碳酸酯重排的合成应用：氯霉素和4-表-胞x酮的对映选择性合成
2. Synthetic applications of the amino-Cope rearrangement: enantioselective synthesis of some tetrahydropyrans [J] . Steven M. Allin, Robert D. Baird, Roger J. Lins Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2002 ,第23期

机译：氨基-Cope重排的合成应用：一些四氢吡喃的对映选择性合成
3. Highly Enantioselective Carbon-carbon Bond Formation By Cu-catalyzed Asymmetric [2,3]-sigmatropic Rearrangement: Application To The Syntheses Of Seven-membered Oxacycles And Six-membered Carbocycles [J] . Gullapalli Kumaraswamy, Kadivendi Sadaiah, Duggirala Subrahmanya Ramakrishna, Chemical Communications . 2008 ,第42期

机译：铜催化的不对称[2,3]-σ重排的高对映选择性碳-碳键形成：在七元氧杂环和六元碳环的合成中的应用
4. Synthetic Applications of Enantioselective Protonation and Case Study for(S)-a-Damascone [C] . Charles Fehr, Harvey Randall RSC/SCI "Flavours Fragrances" Conference . 2008

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5. I. Copper-catalyzed enantioselective Claisen rearrangement. II. Advances in super silyl chemistry through the development of new synthetic methodologies [D] . Tan, Jiajing 2013

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6. Catalytic Enantioselective Silylation of Acyclic and Cyclic Triols: Application to Total Syntheses of Cleroindicins D F and C [O] . Zhen You, Amir H. Hoveyda, Marc L. Snapper -1

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7. Tungsten-mediated syntheses, skeletal rearrangement and synthetic applications of η1-2,5-dihydro-3-furanyl rings [O] . CHENG MH 2011

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Synthetic applications of the cyclic iminocarbonate rearrangement: enantioselective syntheses of chloramphenicol and 4-epi-cytoxazone

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