STEREOSELECTIVE REDUCTION OF ALPHA,BETA-EPOXY KETONES WITH SODIUM BOROHYDRIDE IN THE PRESENCE OF CALCIUM CHLORIDE OR LANTHANUM CHLORIDE - A PRACTICAL PREPARATION OF ERYTHRO-ALPHA,BETA-EPOXY ALCOHOLS

Taniguchi M.; Oshima K.; Utimoto K.; Fujii H.

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STEREOSELECTIVE REDUCTION OF ALPHA,BETA-EPOXY KETONES WITH SODIUM BOROHYDRIDE IN THE PRESENCE OF CALCIUM CHLORIDE OR LANTHANUM CHLORIDE - A PRACTICAL PREPARATION OF ERYTHRO-ALPHA,BETA-EPOXY ALCOHOLS

机译：在存在氯化钙或氯化镧的情况下，用硼氢化钠立体选择性还原α-贝塔酮-酮-一种实用的红α-贝塔酮醇的制备方法

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erythro-Epoxy alcohols were prepared with high stereoselectivity by NaBH4 reduction of the corresponding alpha,beta-epoxy ketones in the presence of calcium chloride or lanthanum chloride regardless of the substituents on the epoxide ring. [References: 16]

机译：通过在氯化钙或氯化镧存在下，通过NaBH4还原相应的α，β-环氧酮，以高立体选择性制备赤型-环氧醇，而与环氧环上的取代基无关。 [参考：16]

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《Tetrahedron》 |1995年第3期|共8页
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Taniguchi M.; Oshima K.; Utimoto K.; Fujii H.;
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1. STEREOSELECTIVE REDUCTION OF ALPHA,BETA-EPOXY KETONES WITH SODIUM BOROHYDRIDE IN THE PRESENCE OF CALCIUM CHLORIDE OR LANTHANUM CHLORIDE - A PRACTICAL PREPARATION OF ERYTHRO-ALPHA,BETA-EPOXY ALCOHOLS [J] . Taniguchi M., Oshima K., Utimoto K., Tetrahedron . 1995,第3期

机译：在存在氯化钙或氯化镧的情况下，用硼氢化钠立体选择性还原α-贝塔酮-酮-一种实用的红α-贝塔酮醇的制备方法
2. Stereoselective sodium borohydride reduction, catalyzed by manganese(II) chloride, of #gamma#-oxo-#alpha#-amino acids. A practical approach to syn-#gamma#-hydroxy-#alpha#-amino acids [J] . Berkes Dusan, Kolarovic Andrej, Povazanec Frantisek Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2000,第27期

机译：氯化锰（II）催化的＃γ＃-氧代-＃α＃-氨基酸的立体选择性硼氢化钠还原。一种合成-γ-羟基-α-氨基酸的实用方法
3. Hydrazine hydrate induced reductive cleavage of alpha,beta-epoxy ketones:an efficient procedure for the preparation of p-hydroxy ketones [J] . Jorge A.R.Salvador, Alcino J.L.Leitao, M.Luisa Sa e Melo, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2005,第7期

机译：水合肼诱导的α，β-环氧酮的还原裂解：制备对羟基酮的有效方法
4. Cerium Chloride Catalyzed Reduction Of Aromatic Esters To The Corresponding Alcohols With Sodium Borohydride In Water [C] . Xun Zhu, Yunyang Wei International Conference on Chemical, Material and Metallurgical Engineering . 2012

机译：氯化铈用硼氢化钠在水中将芳族酯的还原物催化到相应的醇中
5. The stereocontrolled synthesis of the water mold hormone (Z)-24(28)-dehydro-oogoniol and the Luche reduction of acyclic and cyclic alpha, beta-epoxy ketones. [D] . Li, Keqiang. 1994

机译：立体控制水霉菌激素（Z）-24（28）-dehydro-oogoniol的合成以及Luche还原无环和环状α，β-环氧酮的作用。
6. Quantitative Determination of Paraquat in Meconium by Sodium Borohydride-Nickel Chloride Chemical Reduction and Gas Chromatography/Mass Spectrometry (GC/MS) [O] . Norberto C. Posecion Jr., Enrique M. Ostrea Jr., Dawn M. Bielawski -1

机译：硼氢化钠-氯化镍化学还原-气相色谱/质谱法（GC / MS）定量测定胎粪中的百草枯
7. Stereoselective sodium borohydride reductions of cyclopentanones: influence of ceric chloride on the stereochemistry of reaction [O] . Mauricio Gomes Constantino, Luiz Gonzaga de Oliveira Matias, Gil Valdo José da Silva, 1998

机译：立体选择性硼氢化钠还原环戊酮：氯化铈对反应立体化学的影响
8. A PROCESS FOR THE SEMIMICRO PREPARATION OF ELEMENTAL LANTHANUM BY REDUCTION OF LANTHANUM BROMIDE OR CHLORIDE BY POTASSIUM VAPOR [R] . WILSON H. POWER, GEORGE L. POX, JOHN B. OTTO 1954

机译：通过钾蒸气还原溴化镧或氯化物半乳糖制备元素镧的方法

STEREOSELECTIVE REDUCTION OF ALPHA,BETA-EPOXY KETONES WITH SODIUM BOROHYDRIDE IN THE PRESENCE OF CALCIUM CHLORIDE OR LANTHANUM CHLORIDE - A PRACTICAL PREPARATION OF ERYTHRO-ALPHA,BETA-EPOXY ALCOHOLS

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