RADICAL CYCLIZATION OF ALPHA-ALLENIC KETONE - A NEW APPROACH TO THE SYNTHESIS OF (+/-)-ALPHA-CHAMIGRENE

Chen YJ.; Lin WY.; Wang CY.

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RADICAL CYCLIZATION OF ALPHA-ALLENIC KETONE - A NEW APPROACH TO THE SYNTHESIS OF (+/-)-ALPHA-CHAMIGRENE

机译：丙二烯酮的自由基循环-一种合成（+/-）-α-紫杉醇的新方法

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A regioselective cyclization of epsilon-alkyl radicals attacking on the sp-carbon of alpha-allenic ketone to construct a spiro[5.5]undecane skeleton has been studied, and a new approach to the synthesis of(+/-)-alpha-chamigrene 22 is also reported. Copyright (C) 1996 Elsevier Science Ltd. [References: 31]

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《Tetrahedron》 |1996年第41期|共8页
作者
Chen YJ.; Lin WY.; Wang CY.;
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正文语种 eng
中图分类有机化学;
关键词
Organic-synthesis; Chain reactions; Heterolysis; Design; Esters;

机译：有机合成链反应裂解酯酯;

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1. RADICAL CYCLIZATION OF ALPHA-ALLENIC KETONE - A NEW APPROACH TO THE SYNTHESIS OF (+/-)-ALPHA-CHAMIGRENE [J] . Chen YJ., Lin WY., Wang CY. Tetrahedron . 1996,第41期

机译：丙二烯酮的自由基循环-一种合成（+/-）-α-紫杉醇的新方法
2. Controlled Synthesis of alpha-Allenic Ester and Spiro Ketone Derivatives from Tailored alpha-Substituted Cycloalkanones Through Cascade Reactions:Exploring the Possible Reaction Pathways by Means of Semiempirical MO Calculations [J] . Antonio J.Mota, Alain Dedieu, Aurelie Klein, European journal of organic chemistry . 2005,第20期

机译：通过级联反应从量身定制的α-取代的环烷酮控制合成α-烯丙基酯和螺酮衍生物：通过半经验MO计算探索可能的反应途径
3. Synthesis of dihydrofurans containing trifluoromethyl ketone and heterocycles by radical cyclization of fluorinated 1,3-dicarbonyl compounds with 2-thienyl and 2-furyl substituted alkenes [J] . Ylmaz M. Tetrahedron . 2011,第43期

机译：通过含2-噻吩基和2-呋喃基取代的烯烃的氟化1,3-二羰基化合物的自由基环化反应合成含三氟甲基酮和杂环的二氢呋喃
4. Electrochemical Synthesis of Heterocycles through Radical Cyclizations [C] . Hai-Chao Xu 日本化学会春季年会講演予稿集 . 2018

机译：通过自由基环化的电化学合成杂环
5. I. Scandium (III) catalyzed Nazarov cyclization of heteroaryl-vinyl ketones. II. Efforts towards the total synthesis of (±)-rocaglamide via a Nazarov cyclization strategy. III. Efforts towards the total synthesis of (±)-rocaglamide via an alkoxy allene epoxidation/Nazarov cyclization [D] . Malona, John A. 2009

机译：I. Scan（III）催化杂芳基-乙烯基酮的纳扎罗夫环化。二。通过Nazarov环化策略实现全合成（±）-rocaglamide的努力。三，通过烷氧基丙二烯环氧化/纳扎罗夫环化全合成（±）-rocaglamide的努力
6. Biocatalytic Conversion of Cyclic Ketones Bearing α‐Quaternary Stereocenters into Lactones in an Enantioselective Radical Approach to Medium‐Sized Carbocycles [O] . Charlotte Morrill, Dr. Chantel Jensen, Dr. Xavier Just‐Baringo, -1

机译：中型碳环化合物的对映选择性自由基方法对带有α-立体立体中心的环酮的生物催化转化为内酯
7. Radical Cyclization in Heterocycle Synthesis 15. Relationship between a Radical Species and Radical Acceptors of Three Different Types of Double Bond in Radical Addition-Cyclization [O] . Okiko Miyata, Seiko Kajisa, Masafumi Ueda, 2005

机译：杂环合成中的自由基环化15.在根本添加环化中三种不同类型双键的自由基物种和自由基受体的关系

RADICAL CYCLIZATION OF ALPHA-ALLENIC KETONE - A NEW APPROACH TO THE SYNTHESIS OF (+/-)-ALPHA-CHAMIGRENE

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