N-prop-2-ynylmaleimide. Application to sequential one-pot Rh(I) catalysed [2+2+2]-alkyne cyclotrimerisation-imine cycloaddition

Grigg R.; Wang J.; Xu J.; Sridharan V.

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N-prop-2-ynylmaleimide. Application to sequential one-pot Rh(I) catalysed [2+2+2]-alkyne cyclotrimerisation-imine cycloaddition

机译：N-丙-2-炔基马来酰亚胺。在连续一锅Rh（I）催化的[2 + 2 + 2]-炔烃环三聚-亚胺环加成反应中的应用

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Rh(I) catalysed [2+2+2]-cyclotrimerisation of 1,6-diynes with monoynes in combination with stereospecific thermal or Ag(I) catalysed aldimine-->(metallo) azomethine ylide-->cycloaddition cascades affords rapid access to complex heterocyclic benzene derivatives in one-pot processes with the generation 5 new bonds, 4 stereocentres and 3 rings. (C) 2000 Elsevier Science Ltd. All rights reserved. [References: 30]

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《Tetrahedron》 |2000年第45期|共10页
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Grigg R.; Wang J.; Xu J.; Sridharan V.;
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正文语种 eng
中图分类有机化学;
关键词
Azomethine ylide; Cycloaddition; Heterocycles; Beta-lactam; Alpha-amino-acids; X=y-zh compounds; Potential 1; 3-dipoles; Cyclic dipolarophiles; Cyclization; Strategy; lt; 2+2+2gt; -cycloadditions; Acetylenes; Systems;

机译：甲亚胺叶立德;环加成;杂环;β-内酰胺;α-氨基酸;X = y-zh化合物;电位1;3-偶极;环状双亲亲;环化;策略;2 + 2 + 2-环加成;乙炔;系统篇;

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1. N-prop-2-ynylmaleimide. Application to sequential one-pot Rh(I) catalysed [2+2+2]-alkyne cyclotrimerisation-imine cycloaddition [J] . Grigg R., Wang J., Xu J., Tetrahedron . 2000,第45期

机译：N-丙-2-炔基马来酰亚胺。在连续一锅Rh（I）催化的[2 + 2 + 2]-炔烃环三聚-亚胺环加成反应中的应用
2. Enantioselective Rhodium-Catalyzed [2+2+2] Cycloaddition of Alkenyl Isocyanates and Terminal Alkynes:Application to the Total Synthesis of (+)-Lasubine II [J] . Robert T.Yu, Tomislav Rovis Journal of the American Chemical Society . 2006,第38期

机译：对映体铑催化的烯基异氰酸酯和末端炔烃的[2 + 2 + 2]环加成反应：在（+）-Lasubine II的全合成中的应用
3. Sequential one-pot Rh(I)/Pd(0) catalysed cycloaddition-cyclisation-anion capture. Assembly of polyfunctional compounds [J] . Grigg R., Zhang J., Sridharan V. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1999,第47期

机译：顺序一锅Rh（I）/ Pd（0）催化的环加成环化阴离子捕获。多官能化合物的组装
4. NbCl3-Catalyzed 2+2+2 Cycloaddition of Alkynes with Alkenes to 1,3-Cyclohexadienes [C] . Keisuke Takeshita, Yasushi Obora, Yasutaka Ishii Symposium on Organometallic Chemistry . 2008

机译：NbCl3催化2 + 2 + 2环加成炔烃与alkenes至1,3-环己烷烯
5. Enantioselective rhodium-catalyzed [2+2+2] and [4+2+2] cycloaddition reactions of alkenyl heterocumulenes: Applications to alkaloid synthesis [D] . Yu, Robert Tzu Hsiang 2009

机译：对映体选择性铑催化的烯基杂枯烯的[2 + 2 + 2]和[4 + 2 + 2]环加成反应：在生物碱合成中的应用
6. Phosphoramidite-Rhodium Complexes as Catalysts for the Asymmetric 2+2+2 Cycloaddition of Alkenyl Isocyanates and Alkynes [O] . Rebecca Keller Friedman, Kevin M. Oberg, Derek M. Dalton, -1

机译：亚磷酰胺 - 铑配合物作为催化剂用于不对称2 + 2 + 2链烯基的异氰酸酯和炔烃环加成
7. Enantioselective Rhodium-Catalyzed 2+2+2 Cycloaddition of Alkenyl Isocyanates and Terminal Alkynes: Application to the Total Synthesis of (+)-Lasubine II [O] . -1

机译：对苯烯基异氰酸酯和末端炔烃的循环加入2 + 2 + 2环加成：应用于（+） - 叶鲁胺II的总合成

N-prop-2-ynylmaleimide. Application to sequential one-pot Rh(I) catalysed [2+2+2]-alkyne cyclotrimerisation-imine cycloaddition

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