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Synthesis of Thermoresponsive SiO2 Composite Modified by Nonionic Organosilicone Surfactant

机译:非离子有机硅表面活性剂改性的热敏性SiO2复合材料的合成

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摘要

Nonionic organosilicone surfactant trisiloxane-modified oligo (propylene oxide-block-ethylene oxide) was selected as the typical modifying agent in the synthesis of thermoresponsive SiO2 composite. Absolute ethanol was used as the reaction medium. The properties of the prepared composite were characterized by transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), contact angle measurement instrument and dynamic light scatter (DLS). The results showed that the low critical solution temperature (LCST) of the composite is consistent with the cloud point of trisiloxane-modified oligo (propylene oxide-block-ethylene oxide).
机译:在热敏性SiO2复合材料的合成中,选择非离子型有机硅表面活性剂三硅氧烷改性的低聚物(环氧丙烷嵌段的环氧乙烷)作为典型的改性剂。使用无水乙醇作为反应介质。通过透射电子显微镜(TEM),X射线光电子能谱(XPS),接触角测量仪和动态光散射(DLS)表征了制备的复合材料的性能。结果表明,复合材料的低临界溶液温度(LCST)与三硅氧烷改性的低聚物(环氧丙烷嵌段的环氧乙烷)的浊点一致。

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