AlEt3-promoted eliminative ring-opening of beta-hydroxy epoxides: highly stereoselective synthesis of terminal alpha-hydroxy olefins

Wang F.; Wang SH.; Tu YQ.; Ren SK.

首页> 外文期刊>Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry >AlEt3-promoted eliminative ring-opening of beta-hydroxy epoxides: highly stereoselective synthesis of terminal alpha-hydroxy olefins

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AlEt3-promoted eliminative ring-opening of beta-hydroxy epoxides: highly stereoselective synthesis of terminal alpha-hydroxy olefins

机译：AlEt3促进消除β-羟基环氧化物的开环：末端α-羟基烯烃的高度立体选择性合成

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AlEt3-promoted eliminative ring-opening of beta-epoxy alcohols leading to alpha-hydroxy olefins is reported. This eliminative ring-opening reaction is shown to be highly stereoselective, thus providing an alternative asymmetric synthesis for a-hydroxy olefins. (C) 2003 Elsevier Ltd. All rights reserved. [References: 24]

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《Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry》 |2003年第15期|共5页
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Wang F.; Wang SH.; Tu YQ.; Ren SK.;
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正文语种 eng
中图分类有机化学;
关键词
Asymmetric epoxidation; Homoallylic alcohols; Acid; Fragmentation; Configuration; Efficient; Reagents; Taxol; Route;

机译：不对称环氧化;均丙醇;酸;裂解;构型;高效;试剂;Taxol;途径;

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1. AlEt3-promoted eliminative ring-opening of beta-hydroxy epoxides: highly stereoselective synthesis of terminal alpha-hydroxy olefins [J] . Wang F., Wang SH., Tu YQ., Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2003,第15期

机译：AlEt3促进消除β-羟基环氧化物的开环：末端α-羟基烯烃的高度立体选择性合成
2. Highly Stereoselective Ring-Opening Addition of Terminal Acetylenes to Bicyclic Olefins Catalyzed by Nickel Complexes [J] . Dinesh Kumar Rayabarapu, Chii-Feng Chiou, Chien-Hong Cheng Organic letters . 2002,第10期

机译：镍配合物催化末端乙炔向双环烯烃的高度立体选择性开环加成
3. One-pot sequential cross-metathesis/hydride reduction: highly stereoselective synthesis of primary (E)-allylic alcohols from terminal olefins [J] . Tapas Paul, Gopal Sirasani, Rodrigo B. Andrade Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2008,第21期

机译：一锅顺序交叉复分解/氢化物还原：由末端烯烃高度立体选择性地合成伯（E）-烯丙基醇
4. Stereoselective synthesis and use of vinyl epoxides displaying a Morita-Baylis-Hillman backbone(Abstracts) [C] . Marion Davoust, Jean-Francois, Briere European Symposium on Organic Chemistry . 2007

机译：立体选择性合成和使用乙烯基环氧化物展示Morita-Baylis-Hillman骨架（摘要）
5. Applications of highly reactive carbenoids and chiral olefins in stereoselective synthesis and bioorthogonal labeling chemistry [D] . Taylor, Michael T. 2012

机译：高反应性类胡萝卜素和手性烯烃在立体选择性合成和生物正交标记化学中的应用
6. Highly Stereoselective Synthesis of Tetrasubstituted Acyclic All-carbon Olefins via Enol Tosylation and Suzuki–Miyaura Coupling [O] . Beryl X. Li, Diane N. Le, Kyle A. Mack, -1

机译：烯醇甲苯磺酸化和铃木-宫浦偶联反应的高立体选择性合成四取代的无环全碳烯烃
7. Highly Cis/Trans-Stereoselective (ONSO)CrCl-Catalyzed Ring-Opening Copolymerization of Norbornene Anhydrides and Epoxides [O] . -1

机译：高度顺应性/反式立体选择（INSO）CRCL催化的降冰片烯酸酐和环氧化物的开环共聚
8. Enolboration 7. Dicyclohexyliodoborane, a Highly Stereoselective Reagent For theEnolboration Of Tertiary Amides. Effects of Solvent And Aldolization Temperature on Stereochemistry Achieving the Stereoselective Synthesis of Either Syn or Anti Aldols [R] . Ganesan, K., Brown, H. C. 1994

机译：配合7.二环己基碘硼烷，一种高立体选择性试剂，用于叔酰胺的合成。溶剂和醛醇化温度对立体化学实现syn或anti aldols立体选择性合成的影响

AlEt3-promoted eliminative ring-opening of beta-hydroxy epoxides: highly stereoselective synthesis of terminal alpha-hydroxy olefins

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