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Phase Transitions in Liquid-Crystalline Cyanoethyl Cellulose Solutions in Magnetic Field

机译:液体液晶氰乙基纤维素溶液在磁场中的相变

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摘要

The cloud-point method and polarization microscopy have been used to investigate the phase transitions and the phase state of cyanoethyl cellulose-dimethylacetamide and cyanoethyl cellulose-dimethylform-amide systems in the presence and absence of magnetic field with the help of polarization photoelectric and magnetic setups. The temperature-concentration region of the existence of the liquid-crystalline phase in solutions widens in the magnetic field; the higher the field strength and polymer concentration, the more pronounced this widening. Cyanoethyl cellulose solutions are found to possess "memory": after the magnetic field is switched-off, the orientation of macromolecules and the increased phase transition temperature are preserved for many hours.
机译:借助极化光电和磁性装置,在存在和不存在磁场的情况下,使用了浊点法和极化显微镜研究了氰乙基纤维素-二甲基乙酰胺和氰乙基纤维素-二甲基甲酰胺体系的相变和相态。 。溶液中液晶相存在的温度集中区域在磁场中变宽。场强和聚合物浓度越高,这种扩展越明显。氰乙基纤维素溶液具有“记忆”功能:关闭磁场后,大分子的取向和升高的相变温度可以保持多个小时。

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