Mechanistic exploration of the intramolecular hydroalkoxylation of allenyl alcohols mediated by organolanthanide complexes: A DFT study

摘要

chemical eqution presantation An efficient route toward functionalised cyclic ethers: Computational mechanistic analysis indicates an operative Ln-O σ-bond insertion mechanism with a turnover-limiting cyclisation for the intramolecular hydroalkoxylation of allenyl alcohols (see scheme).