Experimental and simulation study of thin film silicon solar cells with intermediate reflector

摘要

Optical and electrical simulations were carried out for thin film silicon solar tandem cells with intermediate reflector layer (IRL) between top and bottom cell and compared with experimental external quantum efficiency and current voltage characteristics results. Reference data were collected from a series of tandem cells with different thicknesses of the top cell absorber layer (160-240nm), the bottom cell absorber layer (1750-2100nm), and the transparent conductive oxides based IRL (10-80nm). It turned out that for capturing correctly the influence of the IRL on the light management as a function of the IRL thickness, the conventional semicoherent approach is not sufficient. Whereas the optical properties of a very thin IRL are governed by interference effects that are best calculated using a fully coherent model, increasingly thicker IRL show a more and more incoherent behavior. By taking into account, the interface morphology and angular light distribution within the cell stack an algorithm for the effective IRL reflectivity was proposed that explains the experimental findings very well. The consecutive electrical simulations were carried out with the device simulator ASA. The dependence of short circuit current density j(sc) and fill factor FF on the thickness d(IRL) of the IRL is in qualitative agreement between simulation and experiment showing coincident extrema in j(sc)(d(IRL)) and FF(d(IRL)) at the current matching point. Copyright (c) 2013 John Wiley & Sons, Ltd.