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THE MECHANICAL PROPERTIES OF SIALON-BORON NITRIDE COMPOSITE CERAMICS

机译:氮化硅-硼氮化物复合陶瓷的力学性能

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摘要

The production of sialon and sialon-boron nitride composites using oxidized (up to similar to 15 wt.% O) Si3N4-18 wt.% AlN composite powders resulting from plasma chemical synthesis is studied. Hot pressing of these powders to nonporous state at 1620-1775 degrees C is accompanied by the formation of composites consisting mainly of a mixture of beta-sialon (z = 1.5-2) and o'-sialon. Boron nitride additions in an amount of up to 15 wt.% lead to the formation of composites that contain BN lamellar grains in the matrix of single-phase beta-sialon (z = 1.5-2). The mechanical and tribological characteristics of the composites with micron and submicron grains are examined. It is observed that the dependence of scratch hardness on contact strength is almost linear for the sialon ceramics and sialon-boron nitride composites. The material is removed during machining through intensive brittle fracture. The introduction of boron nitride into sialon ceramics in an amount of more than 5% is accompanied by approximately a tenfold increase in the material removal in machining, making possible turning operations.
机译:研究了使用等离子化学合成方法制备的氧化(最多达到15%(重量)O)Si3N4-18%(重量)AlN复合粉末来生产sialon和sialon-氮化硼复合材料。将这些粉末在1620-1775摄氏度下热压成无孔状态,会形成主要由β-赛隆(z = 1.5-2)和o'-赛隆的混合物组成的复合材料。氮化硼的添加量最高达15 wt。%导致形成在单相β-赛隆(z = 1.5-2)的基体中包含BN层状晶粒的复合材料。研究了具有微米和亚微米晶粒的复合材料的机械和摩擦学特性。可以看出,对于赛隆陶瓷和赛隆-氮化硼复合材料,刮擦硬度对接触强度的依赖性几乎是线性的。在加工过程中,由于强烈的脆性断裂而去除了材料。将氮化硼以超过5%的量引入到sialon陶瓷中,伴随着机加工中材料去除量的大约十倍增加,从而使车削操作成为可能。

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