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Study of the mechanical, thermal, and thermodegradative properties of virgin PP with recycled and non-recycled HDPE

机译:用回收的和未回收的HDPE研究纯聚丙烯的机械,热和热降解性能

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In order to show the significance of plastic recycling, a study of the properties of blends of PP with non-recycled and recycled high density polyethylene (HDPE) is made. The results of the Young's modulus for polypropylene (PP)on-recycled and recycled HDPE blends present a slight synergism, although no significant dependence of this property on the compound was observed. The values of elongation at break and ipmact strength reflect the incompatibility of the blends. In thermal studies of the blends, the values of fusion enthalpy are below the values of the components. The results of the thermodegradative studies show that activation energies (E sub a ) obtained are lower, in the case of the blends, than the E sub a corresponding to pure polymers. In PP /recycled HDPE blends, activation energy, at 5-20% concentration, is maintained and falls abruptly with an increase in the concentration of the recycled material. Based upon the facts previously exposed, it is possible to recycle the recycled HPDE up to 20% concentration, in PP blends. The addition of the compatibilizer at 5% represents the optimal concentration for improving the final properties of the finished product.
机译:为了显示塑料回收的重要性,对PP与未回收和回收的高密度聚乙烯(HDPE)的混合物的性能进行了研究。聚丙烯(PP)/未回收和回收的HDPE共混物的杨氏模量结果显示出轻微的协同作用,尽管未观察到该性质对化合物的显着依赖性。断裂伸长率和冲击强度的值反映了共混物的不相容性。在共混物的热学研究中,熔融焓的值低于组分的值。热降解研究的结果表明,在共混物的情况下,获得的活化能(E sub a)比对应于纯聚合物的E sub a低。在PP /回收的HDPE共混物中,活化能保持在5-20%的浓度,并且随着回收材料浓度的增加而突然下降。根据先前暴露的事实,有可能在PP共混物中回收高达20%浓度的回收HPDE。添加5%的增容剂代表用于改善最终产品的最终性能的最佳浓度。

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