Effects of the Accelerated Freeze-Thaw Cycling on Physical and Mechanical Properties of Wood Flour-Recycled Thermoplastic Composites

摘要

This study investigated durability performance of wood-plastic composites (WPCs) that were exposed to accelerated cycling of water immersion followed by freeze thaw (FT). The WPCs used in this study were made of high-density polyethylene (HDPE) or polypropylene (PP) with radiata pine (Pinus radiata) wood flour using hot-press molding. These two types of plastics included both recycled and virgin forms in the formulation. In the experiments, surface color, flexural properties, and dimensional stability properties (water absorption and thickness swelling) were measured for the FT cycled composites and the control samples. Interface microstructures and thermal properties of the composites were also investigated. The results show that the water absorption and the thickness swelling of the composites increased with the FT weathering. In the meantime, the flexural strength and stiffness decreased. Scanning electron microscopy (SEM) images of the fractured surfaces confirmed a loss of interface bonding between the wood flour and the polymer matrix. Differential scanning calorimetry (DSC) showed a decrease in crystallization enthalpy and crys-tallinity of the wood flour-plastic composites as compared with the neat PP and HDPE samples. The crystal-linity of the FT cycled composites using the virgin plastics (vPP and vHDPE) increased; however, the composites with the recycled plastics decreased in comparison with corresponding control samples. In general, the properties of the composites were degraded significantly after the accelerated FT cycling.