The Synthesis,Spectroscopic Investigation,Crystal and Molecular Structure of the [ReCl_2(N_2COPh)(2,3'-bpy)(PPh_3)_2] Complex

摘要

The [ReCl_2(N_2COPh)(2,3'-bpy)(PPh_3)_2] complex has been obtained in the reaction of [ReCl_2(eta~2-N_2COPh-N',O)(PPh_3)_2] with an excess of 2,3'-bipyridyl.The [ReCl_2(N_2COPh)(2,3'-bpy)(PPh_3)_2] complex crystallizes in the triclinic space group P-1.The complex was characterized by IR,UV-VIS,and magnetical measurements.The geometries of the complex was optimized with the DFT method.