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Asymptotic laws for tagged-particle motion in glassy systems

机译:玻璃系统中标记粒子运动的渐近定律

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Within mode-coupling theory for structural relaxation in simple systems, the asymptotic laws and their leading-asymptotic correction formulas are derived for the motion of a tagged particle near a glass-transition singularity. These analytic results are compared with numerical ones of the equations of motion evaluated for a tagged hard sphere moving in a hard-sphere system. It is found that the long-time part of the two-step relaxation process for the mean-squared displacement can be characterized by the a-relaxation scaling law and von Schweidler's power-law decay, while the critical-decay regime is dominated by the corrections to the leading power-law behavior. For parameters of interest for the interpretations of experimental data, the corrections to the leading asymptotic laws for the non-Gaussian parameter are found to be so large that the leading asymptotic results are altered qualitatively by the corrections. Results for the non-Gaussian parameter an shown to follow qualitatively the findings reported in the molecular-dynamics-simulations work by Kob and Andersen. [References: 43]
机译:在用于简单系统中结构弛豫的模式耦合理论中,针对玻璃化奇异点附近的带标签粒子的运动,导出了渐近定律及其超前渐进校正公式。将这些分析结果与为在硬球系统中移动的带标签硬球评估的运动方程的数值进行比较。发现均方位移的两步松弛过程的长时间部分可以通过a松弛定标定律和von Schweidler的幂定律衰减来表征,而临界衰变则以更正主要的权力法行为。对于解释实验数据感兴趣的参数,发现对非高斯参数的超前渐近定律的校正是如此之大,以至于校正导致了超前渐近结果的定性改变。非高斯参数的结果定性地遵循了Kob和Andersen在分子动力学模拟研究中报告的发现。 [参考:43]

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