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Conformations of randomly linked polymers

机译:随机连接的聚合物的构象

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We consider polymers in which M randomly selected pairs of monomers are restricted to be in contact. Analytical arguments and numerical simulations show that an ideal (Gaussian) chain of N monomers remains expanded as long as M much less than N, its mean squared end to end distance growing as r(2) proportional to M/N. A possible collapse transition (to a region of order unity) is related to percolation in a one-dimensional model with long-ranged connections. A directed version of the model is also solved exactly. Based on these results, we conjecture that the typical size of a self-avoiding polymer is reduced by the links to R greater than or similar to(N/M)(nu). The number of links needed to collapse a polymer in three dimensions thus scales as N-phi, with phi greater than or similar to 0.43.
机译:我们认为其中M个随机选择的单体对被限制接触的聚合物。分析论证和数值模拟表明,只要M远小于N,理想的N单体链(高斯链)仍保持扩展状态,其平均端到端距离与r / 2成正比,与r / 2成正比。可能的塌陷过渡(到一个有序的区域)与具有长距离连接的一维模型中的渗滤有关。该模型的有向版本也可以精确求解。基于这些结果,我们推测,与(N / M)(nu)的R的连接使自规避聚合物的典型尺寸减小。因此,使聚合物在三个维度上塌缩所需的链节数量按N-phi缩放,phi大于或等于0.43。

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