...
首页> 外文期刊>Physical review, E >Influence of intermolecular forces at critical-point wedge filling
【24h】

Influence of intermolecular forces at critical-point wedge filling

机译:分子间力对临界点楔形填充的影响

获取原文
获取原文并翻译 | 示例
   

获取外文期刊封面封底 >>

       

摘要

We usemicroscopic density functional theory to study filling transitions in systems with long-ranged wall-fluid and short-ranged fluid-fluid forces occurring in a right-angle wedge. By changing the strength of the wall-fluid interaction we can induce both wetting and filling transitions over a wide range of temperatures and study the order of these transitions. At low temperatures we find that both wetting and filling transitions are first order in keeping with predictions of simple local effective Hamiltonian models. However close to the bulk critical point the filling transition is observed to be continuous even though the wetting transition remains first order and the wetting binding potential still exhibits a small activation barrier. The critical singularities for adsorption for the continuous filling transitions depend on whether retarded or nonretarded wall-fluid forces are present and are in excellent agreement with predictions of effective Hamiltonian theory even though the change in the order of the transition was not anticipated.
机译:我们使用微观密度泛函理论来研究在直角楔形体中发生长距离壁流体和短距离流体流体力的系统中的填充跃迁。通过改变壁-流体相互作用的强度,我们可以在很宽的温度范围内诱导润湿和填充转变,并研究这些转变的顺序。在低温下,我们发现润湿和填充转变都是一阶的,这与简单的局部有效哈密顿量模型的预测相符。然而,即使在接近本体临界点时,也观察到填充过渡是连续的,即使润湿过渡保持一阶并且润湿结合势仍表现出小的活化势垒。对于连续填充过渡,吸附的临界奇异性取决于是否存在滞后的或非滞后的壁液力,即使未预料到过渡顺序的变化,也与有效汉密尔顿理论的预测高度吻合。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号