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Film-form dye adsorbents of NiO: Synthesis, biological activity and application on dye sorption

机译:薄膜状NiO染料吸附剂的合成,生物活性及其在染料吸附中的应用

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摘要

Nowadays dye and agrichemical contaminations are becoming a severe environmental problem and subsequently a low-cost and effective method to eliminate the contaminations is becoming impending. In this study, a facile chemical precipitation method was developed to fabricate series of NiO coatings on porous alumina matrix. Scanning electron microscope, energy dispersive X-ray and powder X-ray diffraction confirmed the formation of meshy and crystalline NiO coatings. Moreover, the pore size, specific surface area and hydrophilic/hydrophobic properties could be adjusted by changing the matrix pore sizes. The biological assays revealed that NiO coatings could restrain the attachment of Aspergillus niger and exhibit a toxicity to the metabolism, proliferation and spread of N1H 3T3 cells. Additionally, the dye sorption capacity of coatings was investigated by employing Congo red as the model compound. The results indicated that the dye sorption capacity of coatings was affected by its surface features, including specific surface area and hydrophilic/hydrophobic properties. It could be concluded that film-form NiO products with special surface features had the potential as dye adsorbents for wastewater treatment.
机译:如今,染料和农业化学污染正成为严重的环境问题,随后,消除污染的低成本有效方法变得迫在眉睫。在这项研究中,开发了一种简便的化学沉淀方法来在多孔氧化铝基体上制造一系列NiO涂层。扫描电子显微镜,能量色散X射线和粉末X射线衍射证实了网状和结晶NiO涂层的形成。此外,可以通过改变基质的孔径来调节孔径,比表面积和亲水/疏水性能。生物学分析表明,NiO涂层可以抑制黑曲霉的附着,并对N1H 3T3细胞的代谢,增殖和扩散具有毒性。另外,通过使用刚果红作为模型化合物研究了涂料对染料的吸附能力。结果表明,涂​​层的染料吸附能力受其表面特征的影响,包括比表面积和亲水/疏水性能。可以得出结论,具有特殊表面特征的薄膜状NiO产品具有作为染料吸附剂用于废水处理的潜力。

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