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The ecological impact of membrane-based extraction of phenolic compounds a life cycle assessment study

机译:膜基酚类化合物提取的生态影响生命周期评估研究

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摘要

Many phenolic compounds show high boiling points, low molecular weights, moderate polaritiesnor high toxicities. Therefore, conventional wastewater treatment is limited or expensive.nRecycling of the separated compounds is often not possible. But, if liquid-liquid reactivenextraction is linked to a non-porous membrane, some or all of the above mentioned limitationsnmay be overcome. The key element is a composite membrane with a dense, hydrophobic topnlayer which avoids the mixing of the two aqueous fluid streams. The dilute phenol stream isnone of them, the other is caustic soda as stripping solvent. Since the basics of this technologynhave been discussed before, the scope of this study is to facilitate process implementationnand integration. To this end, a life cycle assessment framework is used to identify the optimalnequipment size for the treatment of wastewater that may, for example, originate fromnthe production of polycarbonate. Limiting for this application is not the environmentalnperformance though, but most likely process economics.
机译:许多酚类化合物显示高沸点,低分子量,中等极性或高毒性。因此,常规的废水处理是有限的或昂贵的。n分离出的化合物的再循环通常是不可能的。但是,如果液-液反应性吸附与无孔膜相连,则可以克服上述限制中的一些或全部。关键要素是具有致密疏水顶层的复合膜,可避免两种水性流体的混合。稀苯酚物流不是其中的一种,另一种是苛性苏打作为汽提溶剂。由于之前已经讨论了该技术的基础,因此本研究的范围是促进过程实现和集成。为此,使用生命周期评估框架来确定用于处理废水的最佳设备尺寸,例如,废水可能源于聚碳酸酯的生产。对此应用程序的限制不是环境性能,而是最有可能的过程经济学。

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