A New 2D Coordination Polymer Material Based on 4d-4f Heterometallic Assembly

摘要

A new transition-lanthanide metal-organic framework coordination complex, namely [Ag₂Dy(nic)₄(H₂O)₄?· ClO₄?· H₂O]n (nic = nicotinate) (1) has been synthesized by the reaction of the 4d and 4f metal salts with heterocyclic ligand under mild condition and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Compound 1 presents interesting 2D under heterometallic layer generated by the self-assembly of 1D chains of lanthanide-carboxylate with Ag(nic)₂ subunits. Furthermore, the title compound displays an interesting 3D zeolite-like porous topology.View full textDownload full textKeywordscrystal structure, heterometallic complex, porous frameworkRelated var addthis_config = { ui_cobrand: "Taylor & Francis Online", services_compact: "citeulike,netvibes,twitter,technorati,delicious,linkedin,facebook,stumbleupon,digg,google,more", pubid: "ra-4dff56cd6bb1830b" }; Add to shortlist Link Permalink http://dx.doi.org/10.1080/15533170903492713