Chemiresistive ionogel sensor array for the detection and discrimination of volatile organic vapor

摘要

A chemiresistive sensor array consisting of nine different types of ionogels was constructed. The conductivity of each ionogel was very sensitive to stimulations of volatile organic compounds (VOCs). The sensing mechanism of the ionogel was based on the change in ion mobility in response to the absorption of VOCs. This mechanism significantly differed from the currently used chemiresistive sensors, usually relying on the modulation of charge densities. The ionogel sensor can produce a reversible and fast resistance response upon exposure to dosing gases cycled between the VOC sample and N_2. The resistance response of ionogel had a linear relationship with the VOC concentration. Meanwhile, the ionogel sensor displayed selectivity to different types of VOCs because of the specific molecular interaction between ionic liquids and the target organic vapor. A chemiresistive sensor array comprising nine types of ionogel with diverse chemical structures can generate a pattern of cross-reactive responses to a specific vapor, thereby leading to the discrimination of VOCs in air samples using principal component analysis.