Gas sensor properties of Ag- and Pd-decorated SnO micro-disks to NO_2, H_2 and CO: Catalyst enhanced sensor response and selectivity

摘要

The gas sensor response of tin monoxide micro-disks, functionalized with noble metal nanoparticles (Pd and Ag), to NO_2, H_2 and CO were studied by monitoring changes in their resistance upon exposure to the various gases. The tin monoxide, with unusually low Sn oxidation state, was synthetized by carbothermal reduction. Surface modification by Pd and Ag catalysts was achieved by coating the micro-disks by metallic nanoparticle dispersions, prepared by the polyol reduction process, followed by thermal treatment. SEM and TEM analysis showed nanoparticles to be well-dispersed over the SnO surfaces. The decorated SnO micro-disks exhibited high sensor response to reducing gases such as H_2 and CO. On the other hand, the catalytic particles tended to reduce the sensor response to oxidizing gases such as NO_2. The catalytic activity of Pd nanoparticles was tied to chemical sensitization while that of Ag nanoparticles to electronic sensitization. Impedance spectroscopy enabled deconvolution of different contributions to the sensor response with only the Ag-decorated specimens exhibiting two RC time constants. Thus, in contrast to undecorated and Pd-decorated specimens, nearly 80% of Ag modified SnO's response to H_2 was controlled by changes in the interface between particles and disks. Sensor response to H_2 was optimal at higher temperatures (300 ℃), NO_2 at 200 ℃ while that for Pd-decorated materials; maximum sensor response to CO was observed at lower temperatures (under 150℃), where CO absorption by metal nanoparticles is favored.