Structural Features and Initiating Properties of the Hexaadduct of Polystyryllithium and Fullerene C_(60) in Tetrahydrofuran and Their Role in Synthesis of Heteroarm Star-Like Polymers

摘要

Structural transformations of the hexaadduct of polystyryllithium and fullerene C_(60) in the course of interaction with a proton donor or 1,1-diphenylethylene and at initiation of styrene polymerization were studied, and their role in the formation of heteroarm star-like polymers with C_(60) center of branching and arms of polystyrene and poly-2-vinylpyridine was elucidated.