Studies of the Henry reaction catalyzed by Cu–O and Zn–O complexes with dimethoxysilane-bridged derivatives

Luo Mei; Han Bing Yang; Shu Song

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Studies of the Henry reaction catalyzed by Cu–O and Zn–O complexes with dimethoxysilane-bridged derivatives

机译：Cu-O和Zn-O配合物与二甲氧基硅烷桥连衍生物催化的亨利反应研究

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Dimethyldimethoxysilane, methylphenyldimethoxysilane, and diphenyldimethoxysilane have been synthesized by a one-step, simple method and used as catalysts in the Henry reaction with Cu(OAc)₂·H₂O and Zn(OAc)₂·2H₂O, affording 60–96% conversion under the optimum catalytic conditions.

机译：通过一步法，简单的方法合成了二甲基二甲氧基硅烷，甲基苯基二甲氧基硅烷和二苯基二甲氧基硅烷，并将其用作与Cu（OAc）_{2 ·H _{2 O和Zn（OAc）_{2 ·2H _{2 O在最佳催化条件下转化率为60-96％。}}}}

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《Research on Chemical Intermediates》 |2010年第2期|p.181-191|共11页
作者
Luo Mei; Han Bing Yang; Shu Song;
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正文语种 eng
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Dimethyldimethoxysilane; Methylphenyldimethoxysilane; Diphenyldimethoxysilane; Co; catalysts; Henry reaction;

机译：二甲基二甲氧基硅烷;甲基苯基二甲氧基硅烷;二苯二甲氧基硅烷;助催化剂亨利反应;

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1. Studies of the Henry reaction catalyzed by Cu–O and Zn–O complexes with dimethoxysilane-bridged derivatives [J] . Luo Mei, Han Bing Yang, Shu Song Research on Chemical Intermediates . 2010,第2期

机译：Cu-O和Zn-O配合物与二甲氧基硅烷桥连衍生物催化的亨利反应研究
2. Structural and kinetic studies of the polymerization reactions of ε-caprolactone catalyzed by (pyrazol-1-ylmethyl)pyridine Cu(ii) and Zn(ii) complexes [J] . Ojwach S.O., Okemwa T.T., Attandoh N.W., Dalton transactions: An international journal of inorganic chemistry . 2013,第30期

机译：（吡唑-1-基甲基）吡啶Cu（ii）和Zn（ii）配合物催化ε-己内酯聚合反应的结构和动力学研究
3. Redox Reactions of Peroxo Terpyridine Complexes of Cu(II),Zn(II), and Cu(II)-Zn(II):A Pulse Radiolysis Study [J] . KAPOOR SUDHIR, SASTRY M.S. International Journal of Chemical Kinetics . 2000,第2aJuna期

机译：Cu（II），Zn（II）和Cu（II）-Zn（II）的过氧三联吡啶配合物的氧化还原反应：脉冲辐解研究
4. One-Pot Syntheses of 2,3-Dihydrothiopyran-4-one Derivatives by Pd/Cu-Catalyzed Reactions of α,β-Unsaturated Thioesters with Propargyl Alcohols [C] . Yasunori Minami, Hitoshi Kuniyasu, Nobuaki Kambe Symposium on Organometallic Chemistry . 2008

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5. Asymmetric domino Michael-Henry reaction of 1,2-diones with nitroolefins catalyzed by chiral Ni(II) complexes [D] . Liang, Qian 2015

机译：Ni（II）配合物催化1,2-二酮与硝基烯烃的不对称多米诺-迈克尔-亨利反应
6. Cu (II)-Catalyzed Asymmetric Henry Reaction with a Novel C1-Symmetric Aminopinane-Derived Ligand [O] . Liudmila Filippova, Yngve Stenstrøm, Trond Vidar Hansen 2015

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7. Synthesis, structures, nuclease activity, cytotoxicity, DFT and molecular docking studies of two nitrato bridged homodinuclear (Cu-Cu, Zn-Zn) complexes containing 2,2?-bipyridine and a chalcone derivative [O] . Gaur, Ruchi, Choubey, Diksha Kumari, Usman, Mohammad, 2017

机译：两种含2,2′-联吡啶和查耳酮衍生物的硝基桥联同核（Cu-Cu，Zn-Zn）复合物的合成，结构，核酸酶活性，细胞毒性，DFT和分子对接研究
8. Phase Transfer Pd(O) Catalyzed Polymerization Reactions. 1. Synthesis of 1,2-(4,4'-Dialkoxyaryl)Acetylene Monomers and 1,4-Bis(2-(4',4''-Dialkoxyphenyl)Ethynyl)Benzene Derivatives by Phase Transfer Pd(O)/Cu(I) Catalyzed Coupling Reactions. [R] . Pugh, C., Percec, V. 1990

机译：相转移pd（O）催化的聚合反应。 1.相转移pd（O）/ Cu合成1,2-（4,4'-二烷氧基芳基）乙炔单体和1,4-双（2-（4'，4'-二烷氧基苯基）乙炔基）苯衍生物（I）催化的偶联反应。

Studies of the Henry reaction catalyzed by Cu–O and Zn–O complexes with dimethoxysilane-bridged derivatives

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