Transesterification of palm oil using KF and NaNO_3 catalysts supported on spherical millimetric γ-Al_2O_3

摘要

The use of spherical millimetric gamma-alumina (γ-Al_2O_3) as a catalyst support for the production of biodiesel from palm oil is demonstrated. The catalyst support was produced using a dripping method, and KF and NaNO_3 catalysts were loaded on the support using the impregnation method. X-ray diffraction (XRD) analysis showed the formation of Na_2O and NaAlO2 phases on the NaNO_3/γ-Al2O_3 catalyst and the formation of K_2O and KAIF4 on the KF/Y-Al_2O_3 catalyst, which were possibly the active sites for the transesterification reaction. The highest number and strength of basic sites generated from the solid phase reaction of the KF/γ-Al_2O_3 catalyst loaded with 0.24 g kF/g γ-A1_2O_3 and the NaNO_3/γ-Al_2O_3 catalyst loaded with 0.30 g NaNO_3/g γ-Al_2O_3 were confirmed by temperature programmed desorption of CO_2 (CO2-TPD) analysis. The nitrogen adsorption-desorption isotherms also revealed a mesoporous structure of the catalysts. The biodiesel yield was comparable to that produced from smaller catalysts, and this result indicated the potential of the macrospherical catalysts.