An investigation of the thermal and (bio)degradability of PBS copolyesters based on isosorbide

摘要

As an essential biodegradable polyester species, poly(butylene succinate) (PBS) is restricted for wider applications due to its low thermal/mechanical properties and unsatisfactory (bio)degradability. Current practice of introducing either stiff or flexible building blocks into PBS main chains remains challenging to achieve a synergistic enhancement of the thermal and (bio)degradability of this material. We herewith report a series of PBS copolyesters based on the carbohydrate-derived isosorbide (1,4:3,6-dianhydro-D-glucidol, IS) (PBIS) by utilizing its unique intrinsic characters of being rigid and hydrophilic. The target copolyesters were constructed with a broad scope of IS content (0-100 mol%) and with random microstructures. The M-n values and the intrinsic viscosities of these polyesters are in the scopes of 7300 -38,700 g mol(-1) and 0.33-0.82 dL g(-1), respectively. The results shown in this work clearly demonstrated that the presence of IS enhances the T-g values almost linearly and simultaneously promotes (neutral, acidic) hydrolytic and enzymatic degradations (with porcine pancreas) of the copolyesters. PBIS copolyester containing 20 mol% IS displays comparable hydrolytic and enzymatic degradation rates with those of PBSA (20 mol% adipic acid), but a substantially 23 degrees C higher T-g value. Detailed characterization of the molecular structures, micro-sequential structures, molecular weights and polydipersities, thermal properties, hydrophilicities and (bio)degradability are provided. The (bio)degradation and degradation mechanism study of these copolyesters are reported for the first time. (C) 2019 Elsevier Ltd. All rights reserved.