Air Gaps as Intermediate Selective Reflectors to Reach Theoretical Efficiency Limits of Multibandgap Solar Cells

摘要

Efficient external luminescence is a prerequisite for high-voltage solar cells. To approach the Shockley–Queisser limit, a highly reflective rear mirror is required. This mirror enhances the voltage of the solar cell by providing internally luminescent photons with multiple opportunities for escaping out the front surface. Likewise, intermediate reflectors in a multibandgap solar cell can assist external luminescence to enhance the voltage for each cell in a stack. These intermediate reflectors must also transmit the subbandgap photons to the next cell in the stack. A practical implementation of an intermediate selective reflector is an air gap sandwiched by antireflection coatings. The air gap provides perfect reflection for angles outside the escape cone, and the antireflection coating transmits angles inside the escape cone. As the incoming sunlight is within the escape cone, it is transmitted on to the next cell, while most of the internally trapped luminescence is reflected. We calculate that air gap intermediate reflectors, along with a rear mirror, can provide an absolute efficiency increase of ≈5% in multibandgap cells.