The Principles of Gold-Catalyzed Molecular Gymnastics

摘要

Gold(l) orchestrates molecular gymnastics by intra-and intermolecular reaction of enymes via highly distorted cy clopropyl gold carbenes as intermediates. The synthesis of natural products such as (+)-orientalol F and (-)-englerin A illustrates the state of the art of gold (I) catalysis for the buildup of molecular complexity.%L'or(l) dirigeix el contorsionisme molecular mitjançant reaccions intramoleculars I intermoleculars d'enins per mitjà d'intermedis ciclopropil o carbens altament distorsionats. La síntesi de productes naturals com (+)-orienalol F I (-)-englerin A mostra l'estat d'art de la catàlisi de l'or(l) per a construir complexitat molecular.