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Effect Of Niobium On The Microstructure And Wear Resistance Of Iron-based Alloy Coating Produced By Plasma Cladding

机译:铌对等离子熔覆铁基合金涂层组织和耐磨性的影响

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The iron-based alloy coatings have been deposited on plain steel using plasma cladding technique. The effects of niobium element on the microstructure and wear resistance property of the iron-based coatings were investigated using scanning electron microscopy (SEM) with energy dispersive spectrum (EDS),X-ray diffraction (XRD) and ball-on-disc wear tester. Results showed that there were γ-(Fe,Ni) austenite and lots of compounds such as Cr_7C_3, Mo_(1.24)Ni_(0.76) and MoSi_2 in the iron-based clad coating. And the carbide NbC formed in the Nb-contained clad coating. The SEM micrographs of the cross section of Nb-free coating revealed that the clad coating had a fine dendritic microstructure which was a typical microstructure of rapidly solidified austenite (γ). With the niobium addition, the rate of solidification varied and the equiaxed grain formed in the clad coating. And Nb also made the microstructure become finer. The Nb-free and Nb-contained clad coatings both owned an excellent wear resistance property compared to 0.45% C carbon steel under dry sliding wear tests. And the wear resistance of Nb-contained clad coating was higher than that of the Nb-free clad coating because the high hardness carbide NbC distributed in clad: coating and the dispersion strengthening in the iron-based clad coating was obvious, which increased the wear resistance of clad coating under dry sliding wear test.
机译:铁基合金涂层已使用等离子熔覆技术沉积在普通钢上。利用能谱仪(EDS),X射线衍射仪(XRD)和圆盘球磨试验机,研究了铌元素对铁基涂层组织和耐磨性能的影响。 。结果表明,铁基复合涂层中存在γ-(Fe,Ni)奥氏体和大量的Cr_7C_3,Mo_(1.24)Ni_(0.76)和MoSi_2等化合物。并且在含Nb的包覆层中形成碳化物NbC。不含Nb涂层的横截面的SEM显微照片显示,该包覆涂层具有良好的树枝状显微组织,这是快速凝固奥氏体(γ)的典型显微组织。随着铌的加入,凝固速率发生变化,在覆层中形成等轴晶粒。 Nb也使组织变得更细。在干式滑动磨损试验中,与0.45%的碳钢相比,无Nb和含Nb的复合涂层均具有出色的耐磨性。含Nb的复合涂层的耐磨性高于无Nb的复合涂层,这是因为高硬度碳化物NbC分布在复合层中:涂层和铁基复合涂层中的分散增强明显,这增加了磨损在干滑动磨损试验下,复合涂层的耐性。

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