Preparation and magnetic characterization of core-shell structure stainless steel/silica nanoparticles

摘要

SiO_2-coated martensite stainless steel nanoparticles were prepared using wire electrical explosion technique combined with sol-gel technique, and their structural and magnetic properties were studied. The coating silica on stainless steel nanoparticles was based on the use of silane coupling agent 3-mercaptopropyltrimethoxysilane (HS-(CH_2)3Si(OCH3)_3, MPTS) as a primer to render the stainless steel surface vitreophilic, thus rendering stainless steel surface compatible with silica. The control over the silica coating layer thickness can be achieved by varying the reaction time. For stainless steel nanoparticles, their saturation and remnant magnetizations decreased upon silica coating, and their saturation magnetizations obviously decreased with increasing the thickness of SiO_2 coating layer. These stainless steel/silica core-shell nanoparticles can be utilized as precursors for making property-tunable magnetic nanoparticles, thin films, and multilayered core-shell structure nanocomposites.