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Mesoporous In_2O_3 with enhanced acetone gas-sensing property

机译:具有提高的丙酮气敏性能的介孔In_2O_3

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摘要

Ordered mesoporous In_2O_3 with controlled morphology have been synthesized using "container effect" nanocasting method. The mesoporous In_2O_3 with larger mesopore size and smaller particle diameter exhibited improved sensitivity (response of 29.8 to 50 ppm of acetone at 300 ℃), faster response and recovery times (0.7 and 14 s) and higher selectivity to acetone. The acetone detection limit is as low as 500 ppb, which favors the precise diagnosis of human diabetes. The enhanced acetone sensing performance benefits from the large surface area with enough sensing active sites, proper pore size for sufficient gas diffusion and small particle size for effective electron depletion.
机译:使用“容器效应”纳米浇铸法合成了形态受控的有序介孔In_2O_3。具有较大中孔尺寸和较小粒径的介孔In_2O_3表现出更高的灵敏度(在300℃下对丙酮的响应为29.8至50 ppm),更快的响应和恢复时间(0.7和14 s)以及对丙酮的更高选择性。丙酮的检出限低至500 ppb,有助于准确诊断人类糖尿病。增强的丙酮感测性能得益于较大的表面积,足够的感测活性位点,适当的孔径以实现足够的气体扩散以及较小的粒径以实现有效的电子耗尽。

著录项

  • 来源
    《Materials Letters》 |2014年第1期|287-291|共5页
  • 作者单位

    School of Materials Science and Engineering, Key Lab of Advanced Ceramics and Machining Technology, Tianjin University, Tianjin 300072, PR China;

    School of Materials Science and Engineering, Key Lab of Advanced Ceramics and Machining Technology, Tianjin University, Tianjin 300072, PR China;

    School of Materials Science and Engineering, Key Lab of Advanced Ceramics and Machining Technology, Tianjin University, Tianjin 300072, PR China;

    School of Materials Science and Engineering, Key Lab of Advanced Ceramics and Machining Technology, Tianjin University, Tianjin 300072, PR China;

    State Key Laboratory of Hollow-fiber Membrane Materials and Membrane Processes, School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, PR China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    In_2O_3; Mesoporous structure; Sensors; Porous materials; Acetone detection;

    机译:In_2O_3;中孔结构;传感器;多孔材料丙酮检测;

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