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Monodispersed In_2O_3 mesoporous nanospheres: One-step facile synthesis and the improved gas-sensing performance

机译:单分散的In_2O_3介孔纳米球:一步式合成和改进的气敏性能

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摘要

Mesoporous In_2O_3 nanospheres were successfully synthesized by a simple solvothermal route, which was performed without the assistance of any additives or templates. The obtained mesoporous I112O_3 nanospheres show high monodispersity with average size about 90 nm and pore size about 2-4 nm. The optical absorption property of the In_2O_3 mesoporous spheres was investigated by UV-vis spec-troscopy, which indicates that the In_2O_3 mesoporous spheres are semiconducting with a direct band gap of 3.1 eV. The gas sensing performance of the as-prepared In_2O_3 mesoporous nanospheres was investigated towards a series of typical organic solvents and fuels. For 100ppm of butanol and ethanol, the mesoporous In_2O_3 demonstrates sensing responses of 59.6 and 29.6, respectively. These values are much higher than those of the reported In_2O_3-based gas sensors and the In_2O_3 powder sample with similar size, indicating the highly enhanced gas sensing performance of In2O_3 mesoporous nanospheres. The obtained In_2O_3 mesoporous nanospheres appear to be a promising sensing material for environmental detection application and would also find applications in catalyst, electrode, or related fields.
机译:介孔的In_2O_3纳米球是通过简单的溶剂热途径成功合成的,该途径无需任何添加剂或模板即可完成。所得的介孔I112O_3纳米球表现出高的单分散性,其平均尺寸为约90nm,孔尺寸为约2-4nm。通过紫外可见光谱研究了In_2O_3介孔球的光吸收性能,这表明In_2O_3介孔球是半导体的,直接带隙为3.1 eV。研究了制备的In_2O_3介孔纳米球对一系列典型的有机溶剂和燃料的气体传感性能。对于100ppm的丁醇和乙醇,中孔In_2O_3的传感响应分别为59.6和29.6。这些值远高于已报道的基于In_2O_3的气体传感器和具有类似尺寸的In_2O_3粉末样品的值,表明In2O_3介孔纳米球的气体传感性能大大提高。所获得的In_2O_3介孔纳米球似乎是有前途的传感材料,可用于环境检测,并且还将在催化剂,电极或相关领域中找到应用。

著录项

  • 来源
    《Sensors and Actuators》 |2015年第12期|977-985|共9页
  • 作者单位

    School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 2l2013, PR China;

    School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 2l2013, PR China;

    School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 2l2013, PR China;

    School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 2l2013, PR China,School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, PR China;

    School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, PR China;

    School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, PR China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Indium oxide; Mesoporous nanospheres; Solvothermal synthesis; Gas sensing; Monodispersity;

    机译:氧化铟介孔纳米球;溶剂热合成;气体感应;单分散性;

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