Synthesis and Photovoltaic Properties of Alternating Conjugated Polymers Derived from Indeno[1,2-b]fluorene and Bithiophene or Thieno[3,2-b]thiophene-Cored Benzothiadiazole

Yangjun Xia; Zhicai He; Junfeng Tong; Bin Li; Chenglong Wang; Yong Cao; Hongbin Wu; Han Young Woo; Duowang Fan

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Synthesis and Photovoltaic Properties of Alternating Conjugated Polymers Derived from Indeno[1,2-b]fluorene and Bithiophene or Thieno[3,2-b]thiophene-Cored Benzothiadiazole

机译：茚并[1,2-b]芴与联噻吩或噻吩并[3,2-b]噻吩类苯并噻二唑的交替共轭聚合物的合成及光伏性能

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Two narrow bandgap copolymers derived from 6,6′,12,12′-tetraoctyl-indeno[1,2-b]fluorene and bithiophene or thieno[3,2-b]thiophene-cored benzothiadiazole are synthesized and characterized. The copolymers show broad absorption in the range 350–700 nm. The application of the copolymers as photovoltaic cells with configurations ITO/PEDOT:PSS/blend/Al and ITO/PEDOT:PSS/blend/interlayer/Al is investigated. A power conversion efficiency (PCE) of approximately 3.0% is achieved under an AM 1.5G solar simulator (80 mW cm−2) for the cells with ITO/PEDOT:PSS/polymer:PC₇₁BM([6,6]-phenyl-C₇₁ butyric acid methyl ester) (1:4)/interlayer/Al.

机译：合成并表征了两种衍生自6,6'，12,12'-四辛基-茚并[1,2-b]芴和联噻吩或噻吩并[3,2-b]噻吩中心的苯并噻二唑的窄带隙共聚物。共聚物在350-700 nm范围内显示出广泛的吸收。研究了共聚物在ITO / PEDOT：PSS / blend / Al和ITO / PEDOT：PSS / blend / interlayer / Al构型的光伏电池中的应用。在AM 1.5G太阳模拟器（80 mW cm -2 ）下，对于具有ITO / PEDOT：PSS / polymer：PC _{的电池，功率转换效率（PCE）达到约3.0％ 71 BM（[6,6]-苯基-C _{71 丁酸甲酯）（1：4）/中间层/ Al。}}

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来源
《Macromolecular Chemistry and Physics》 |2011年第11期|p.1193-1201|共9页
作者
Yangjun Xia; Zhicai He; Junfeng Tong; Bin Li; Chenglong Wang; Yong Cao; Hongbin Wu; Han Young Woo; Duowang Fan;
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作者单位

Key Laboratory of Opto-Electronic Technology and Intelligent Control of Education Ministry, Lanzhou Jiaotong University, Gansu Province, Lanzhou, 730070, P. R. China|Institute of Polymer Optoelectronic Materials and Devices, Key Laboratory of Special Functional Materials and Advanced Manufacturing Technology, South China University of Technology, Guangzhou, 510640, P. R. China;

Institute of Polymer Optoelectronic Materials and Devices, Key Laboratory of Special Functional Materials and Advanced Manufacturing Technology, South China University of Technology, Guangzhou, 510640, P. R. China;

Key Laboratory of Opto-Electronic Technology and Intelligent Control of Education Ministry, Lanzhou Jiaotong University, Gansu Province, Lanzhou, 730070, P. R. China;

College of Chemistry and Chemical Engineering of Northwest Normal University, Gansu Province, Lanzhou, 730070, P. R. China;

Key Laboratory of Opto-Electronic Technology and Intelligent Control of Education Ministry, Lanzhou Jiaotong University, Gansu Province, Lanzhou, 730070, P. R. China;

Institute of Polymer Optoelectronic Materials and Devices, Key Laboratory of Special Functional Materials and Advanced Manufacturing Technology, South China University of Technology, Guangzhou, 510640, P. R. China;

Institute of Polymer Optoelectronic Materials and Devices, Key Laboratory of Special Functional Materials and Advanced Manufacturing Technology, South China University of Technology, Guangzhou, 510640, P. R. China;

Woo Department of Cogno-Mechatronics Engineering (WCU), Pusan National University, Miryang, 627-706, Republic of Korea;

Key Laboratory of Opto-Electronic Technology and Intelligent Control of Education Ministry, Lanzhou Jiaotong University, Gansu Province, Lanzhou, 730070, P. R. China;

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正文语种 eng
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关键词
conjugated polymers; indeno1,2-bfluorene; photovoltaic solar cells, synthesis;

机译：共轭聚合物;茚并[1,2-b]芴;光伏太阳能电池;合成;

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1. Synthesis and photovoltaic properties of alternating conjugated polymers derived from indeno[1,2-b]fluorene and bithiophene or thieno[3,2-b]thiophene- cored benzothiadiazole [J] . Xia Y., He Z., Tong J., Macromolecular chemistry and physics . 2011,第11期

机译：茚并[1,2-b]芴与联噻吩或噻吩并[3,2-b]噻吩-核苯并噻二唑的交替共轭聚合物的合成及光电性能
2. SYNTHESIS AND PHOTOVOLTAIC PROPERTIES OF ALTERNATING CONJUGATED POLYMERS DERIVED FROM INDOLO[3,2-b]CARBAZOLE AND THIOPHENE/THIENO[3,2-b]THIOPHENE-CORED BENZOSELENADIAZOLE [J] . Bin Li, Yangjun Xia, Junfeng Tong Высоκомолеκулярные соединения . 2011,第6期

机译：吲哚[3,2-b]咔唑和噻吩/噻吩[3,2-b]噻吩中心的苯并苯二氮杂唑类共轭聚合物的合成及其光致光伏性能
3. An Alternating Copolymer Derived from Indolo[3,2-b]carbazole and 4,7-Di(thieno[3,2-b]thien-2-yl)-2,1,3-benzothiadiazole for Photovoltaic Cells [J] . Yangjun Xia, Xuehua Su, Zhicai He, Macromolecular Rapid Communications . 2010,第14期

机译：一种由吲哚[3,2-b]咔唑和4,7-二（噻吩[3,2-b]噻二-2-基）-2,1,3-苯并噻二唑衍生的用于光伏电池的交替共聚物
4. Synthesis and Characterization of Trifluoromethylated Benzimidazole and Benzo1,2-B:3,4-B'Dithiophene Based Donor-Acceptor Conjugated Polymer for Polymer Solar Cells [C] . Murali M. G., Arun D. Rao, Praveen C. Ramamurthy Materials Research Society Meeting . 2014

机译：三氟甲基化苯并咪唑和苯并1,2-B：3,4-B'基于聚合物太阳能电池的三噻吩基含量缀合聚合物的合成与表征
5. Structure-property relationships in conjugated oligomers containing thieno[3,2-b]thiophene and thieno[3,2-b]furan [D] . Henssler, John T. 2010

机译：含有噻吩并[3,2-b]噻吩和噻吩并[3,2-b]呋喃的共轭低聚物的结构-性质关系
6. Effect of Flank Rotation on the Photovoltaic Properties of Dithieno[2,3-d:2′,3′-d′]benzo[1,2-b:4,5-b′]dithiophene-Based Narrow Band Gap Copolymers [O] . Mingjing Zhang, Liangjian Zhu, Pengzhi Guo, 2018

机译：侧面旋转对双噻吩[2,3-d：2'，3'-d']苯并[1,2-b：4,5-b']二噻吩基窄带隙共聚物光伏性能的影响
7. Synthesis and Photovoltaic Properties of Alternating Conjugated Polymers Derived from Thiophene-Benzothiadiazole Block and Fluorene/Indenofluorene Units [O] . Jianfeng Li, Junfeng Tong, Peng Zhang, 2014

机译：衍生自噻吩 - 苯并噻唑块和芴/茚或茚单位的交替共轭聚合物的合成和光伏性能

Synthesis and Photovoltaic Properties of Alternating Conjugated Polymers Derived from Indeno[1,2-b]fluorene and Bithiophene or Thieno[3,2-b]thiophene-Cored Benzothiadiazole

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