Electrochemical properties of gel polymer electrolyte based on poly(acrylonitrile)-poly(ethylene glycol diacrylate) blend

摘要

Gel type electrolyte was formulated by blending of PEDGA and PAN. PEDGA is a UV curable polymer which forms a chemical crosslink by UV or heat. Gel type electrolyte is very stable in ionic conductivity and interfacial resistance for a long storage time. It has the advantage of manufacturing the battery in a continuous process because oligomer crosslinking occurs in few seconds without heating. Discharge capacity and cycle life were increased by using LiPF_6/LiCF_3SO_3 mixed lithium salt and adding inorganic filler such as TiO_2.